Relaxation Rate Distributions for Supercooled Liquids
The mode-coupling theory for the evolution of glassy dynamics in simple liquids yields correlation functions that, outside the transient regime, can be written as a superposition of relaxators with a broad distribution of relaxation rates. The known asymptotic laws for the dynamics near an ideal gla...
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Veröffentlicht in: | The journal of physical chemistry. B 1999-05, Vol.103 (20), p.4011-4017 |
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Hauptverfasser: | , |
Format: | Artikel |
Sprache: | eng |
Online-Zugang: | Volltext |
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Zusammenfassung: | The mode-coupling theory for the evolution of glassy dynamics in simple liquids yields correlation functions that, outside the transient regime, can be written as a superposition of relaxators with a broad distribution of relaxation rates. The known asymptotic laws for the dynamics near an ideal glass transition imply corresponding laws for the rate distribution. We calculate the rate distributions for a hard-sphere liquid and compare them to the leading and next-to-leading asymptotic formulas. |
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ISSN: | 1520-6106 1520-5207 |
DOI: | 10.1021/jp983412r |