Relaxation Rate Distributions for Supercooled Liquids

The mode-coupling theory for the evolution of glassy dynamics in simple liquids yields correlation functions that, outside the transient regime, can be written as a superposition of relaxators with a broad distribution of relaxation rates. The known asymptotic laws for the dynamics near an ideal gla...

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Veröffentlicht in:The journal of physical chemistry. B 1999-05, Vol.103 (20), p.4011-4017
Hauptverfasser: Franosch, T, Götze, W
Format: Artikel
Sprache:eng
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Zusammenfassung:The mode-coupling theory for the evolution of glassy dynamics in simple liquids yields correlation functions that, outside the transient regime, can be written as a superposition of relaxators with a broad distribution of relaxation rates. The known asymptotic laws for the dynamics near an ideal glass transition imply corresponding laws for the rate distribution. We calculate the rate distributions for a hard-sphere liquid and compare them to the leading and next-to-leading asymptotic formulas.
ISSN:1520-6106
1520-5207
DOI:10.1021/jp983412r