Laser-Induced Fluorescence Studies of Excited Sr Reactions. † 1. Sr(3P1) + HF

Laser-Induced Fluorescence Studies of Excited Sr Reactions. † 1. Sr(3P1) + HF

Electronic ground-state SrF (X2Σ) products formed in the reaction of electronically excited Sr(3P1) with HF are studied using laser-induced fluorescence (LIF) detection. Sr atoms are excited to the 3P1 state using a frequency-narrowed and -stabilized linear titanium−sapphire laser at 689.3 nm. The v...

Ausführliche Beschreibung

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:The journal of physical chemistry. A, Molecules, spectroscopy, kinetics, environment, & general theory Molecules, spectroscopy, kinetics, environment, & general theory, 1998-11, Vol.102 (47), p.9482-9488
Hauptverfasser: Teule, J. M, Mes, J, Bulthuis, J, Janssen, M. H. M, Stolte, S
Format: Artikel
Sprache:eng
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
container_end_page 9488
container_issue 47
container_start_page 9482
container_title The journal of physical chemistry. A, Molecules, spectroscopy, kinetics, environment, & general theory
container_volume 102
creator Teule, J. M
Mes, J
Bulthuis, J
Janssen, M. H. M
Stolte, S
description Electronic ground-state SrF (X2Σ) products formed in the reaction of electronically excited Sr(3P1) with HF are studied using laser-induced fluorescence (LIF) detection. Sr atoms are excited to the 3P1 state using a frequency-narrowed and -stabilized linear titanium−sapphire laser at 689.3 nm. The vibrational and rotational population distributions in the SrF(X2Σ) products are deduced from the LIF spectra of the B2Σ−X2Σ and A2Π3/2−X2Σ transitions using spectrum simulation. The results show a strong dependence of the SrF internal energy distribution on the impact parameter. The light H atom is ejected with high translational energy.
doi_str_mv 10.1021/jp981993e
format Article
fullrecord <record><control><sourceid>istex_cross</sourceid><recordid>TN_cdi_crossref_primary_10_1021_jp981993e</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>ark_67375_TPS_K3G8T0X0_9</sourcerecordid><originalsourceid>FETCH-LOGICAL-a330t-cded26accb8b76b7a0bc80bcb5ab9e4c1cf168bbbd4a4b666877a5af64f5246a3</originalsourceid><addsrcrecordid>eNptkM1KAzEUhYMoWKsL3yAbwSJTk8kkkyyl9A8LLbaCu3CTycDUOlOSGag7H8Vn80mMVFy5uJzLvR8HzkHompIhJSm93-6VpEoxd4J6lKck4Snlp3EnUiVcMHWOLkLYEkIoS7MeWi4gOJ_M66KzrsCTXdd4F6yrrcPrtisqF3BT4vHBVm38rz1-cmDbqqnDEH99fGI6jMdbtqIDfIdnk0t0VsIuuKtf7aPnyXgzmiWL5XQ-elgkwBhpE1u4IhVgrZEmFyYHYqyMYzgY5TJLbUmFNMYUGWRGCCHzHDiUIit5mglgfTQ4-lrfhOBdqfe-egP_rinRP03ovyYimxzZKrTu8AeCf9UiZznXm9VaP7Kp3JAXolXkb4482KC3TefrmOQf32-zP2uI</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype></control><display><type>article</type><title>Laser-Induced Fluorescence Studies of Excited Sr Reactions. † 1. Sr(3P1) + HF</title><source>ACS Publications</source><creator>Teule, J. M ; Mes, J ; Bulthuis, J ; Janssen, M. H. M ; Stolte, S</creator><creatorcontrib>Teule, J. M ; Mes, J ; Bulthuis, J ; Janssen, M. H. M ; Stolte, S</creatorcontrib><description>Electronic ground-state SrF (X2Σ) products formed in the reaction of electronically excited Sr(3P1) with HF are studied using laser-induced fluorescence (LIF) detection. Sr atoms are excited to the 3P1 state using a frequency-narrowed and -stabilized linear titanium−sapphire laser at 689.3 nm. The vibrational and rotational population distributions in the SrF(X2Σ) products are deduced from the LIF spectra of the B2Σ−X2Σ and A2Π3/2−X2Σ transitions using spectrum simulation. The results show a strong dependence of the SrF internal energy distribution on the impact parameter. The light H atom is ejected with high translational energy.</description><identifier>ISSN: 1089-5639</identifier><identifier>EISSN: 1520-5215</identifier><identifier>DOI: 10.1021/jp981993e</identifier><language>eng</language><publisher>American Chemical Society</publisher><ispartof>The journal of physical chemistry. A, Molecules, spectroscopy, kinetics, environment, &amp; general theory, 1998-11, Vol.102 (47), p.9482-9488</ispartof><rights>Copyright © 1998 American Chemical Society</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-a330t-cded26accb8b76b7a0bc80bcb5ab9e4c1cf168bbbd4a4b666877a5af64f5246a3</citedby><cites>FETCH-LOGICAL-a330t-cded26accb8b76b7a0bc80bcb5ab9e4c1cf168bbbd4a4b666877a5af64f5246a3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://pubs.acs.org/doi/pdf/10.1021/jp981993e$$EPDF$$P50$$Gacs$$H</linktopdf><linktohtml>$$Uhttps://pubs.acs.org/doi/10.1021/jp981993e$$EHTML$$P50$$Gacs$$H</linktohtml><link.rule.ids>314,778,782,2754,27063,27911,27912,56725,56775</link.rule.ids></links><search><creatorcontrib>Teule, J. M</creatorcontrib><creatorcontrib>Mes, J</creatorcontrib><creatorcontrib>Bulthuis, J</creatorcontrib><creatorcontrib>Janssen, M. H. M</creatorcontrib><creatorcontrib>Stolte, S</creatorcontrib><title>Laser-Induced Fluorescence Studies of Excited Sr Reactions. † 1. Sr(3P1) + HF</title><title>The journal of physical chemistry. A, Molecules, spectroscopy, kinetics, environment, &amp; general theory</title><addtitle>J. Phys. Chem. A</addtitle><description>Electronic ground-state SrF (X2Σ) products formed in the reaction of electronically excited Sr(3P1) with HF are studied using laser-induced fluorescence (LIF) detection. Sr atoms are excited to the 3P1 state using a frequency-narrowed and -stabilized linear titanium−sapphire laser at 689.3 nm. The vibrational and rotational population distributions in the SrF(X2Σ) products are deduced from the LIF spectra of the B2Σ−X2Σ and A2Π3/2−X2Σ transitions using spectrum simulation. The results show a strong dependence of the SrF internal energy distribution on the impact parameter. The light H atom is ejected with high translational energy.</description><issn>1089-5639</issn><issn>1520-5215</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>1998</creationdate><recordtype>article</recordtype><recordid>eNptkM1KAzEUhYMoWKsL3yAbwSJTk8kkkyyl9A8LLbaCu3CTycDUOlOSGag7H8Vn80mMVFy5uJzLvR8HzkHompIhJSm93-6VpEoxd4J6lKck4Snlp3EnUiVcMHWOLkLYEkIoS7MeWi4gOJ_M66KzrsCTXdd4F6yrrcPrtisqF3BT4vHBVm38rz1-cmDbqqnDEH99fGI6jMdbtqIDfIdnk0t0VsIuuKtf7aPnyXgzmiWL5XQ-elgkwBhpE1u4IhVgrZEmFyYHYqyMYzgY5TJLbUmFNMYUGWRGCCHzHDiUIit5mglgfTQ4-lrfhOBdqfe-egP_rinRP03ovyYimxzZKrTu8AeCf9UiZznXm9VaP7Kp3JAXolXkb4482KC3TefrmOQf32-zP2uI</recordid><startdate>19981119</startdate><enddate>19981119</enddate><creator>Teule, J. M</creator><creator>Mes, J</creator><creator>Bulthuis, J</creator><creator>Janssen, M. H. M</creator><creator>Stolte, S</creator><general>American Chemical Society</general><scope>BSCLL</scope><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>19981119</creationdate><title>Laser-Induced Fluorescence Studies of Excited Sr Reactions. † 1. Sr(3P1) + HF</title><author>Teule, J. M ; Mes, J ; Bulthuis, J ; Janssen, M. H. M ; Stolte, S</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-a330t-cded26accb8b76b7a0bc80bcb5ab9e4c1cf168bbbd4a4b666877a5af64f5246a3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>1998</creationdate><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Teule, J. M</creatorcontrib><creatorcontrib>Mes, J</creatorcontrib><creatorcontrib>Bulthuis, J</creatorcontrib><creatorcontrib>Janssen, M. H. M</creatorcontrib><creatorcontrib>Stolte, S</creatorcontrib><collection>Istex</collection><collection>CrossRef</collection><jtitle>The journal of physical chemistry. A, Molecules, spectroscopy, kinetics, environment, &amp; general theory</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Teule, J. M</au><au>Mes, J</au><au>Bulthuis, J</au><au>Janssen, M. H. M</au><au>Stolte, S</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Laser-Induced Fluorescence Studies of Excited Sr Reactions. † 1. Sr(3P1) + HF</atitle><jtitle>The journal of physical chemistry. A, Molecules, spectroscopy, kinetics, environment, &amp; general theory</jtitle><addtitle>J. Phys. Chem. A</addtitle><date>1998-11-19</date><risdate>1998</risdate><volume>102</volume><issue>47</issue><spage>9482</spage><epage>9488</epage><pages>9482-9488</pages><issn>1089-5639</issn><eissn>1520-5215</eissn><abstract>Electronic ground-state SrF (X2Σ) products formed in the reaction of electronically excited Sr(3P1) with HF are studied using laser-induced fluorescence (LIF) detection. Sr atoms are excited to the 3P1 state using a frequency-narrowed and -stabilized linear titanium−sapphire laser at 689.3 nm. The vibrational and rotational population distributions in the SrF(X2Σ) products are deduced from the LIF spectra of the B2Σ−X2Σ and A2Π3/2−X2Σ transitions using spectrum simulation. The results show a strong dependence of the SrF internal energy distribution on the impact parameter. The light H atom is ejected with high translational energy.</abstract><pub>American Chemical Society</pub><doi>10.1021/jp981993e</doi><tpages>7</tpages><oa>free_for_read</oa></addata></record>
fulltext fulltext
identifier ISSN: 1089-5639
ispartof The journal of physical chemistry. A, Molecules, spectroscopy, kinetics, environment, & general theory, 1998-11, Vol.102 (47), p.9482-9488
issn 1089-5639
1520-5215
language eng
recordid cdi_crossref_primary_10_1021_jp981993e
source ACS Publications
title Laser-Induced Fluorescence Studies of Excited Sr Reactions. † 1. Sr(3P1) + HF
url https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-01-15T15%3A41%3A59IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-istex_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Laser-Induced%20Fluorescence%20Studies%20of%20Excited%20Sr%20Reactions.%20%E2%80%A0%201.%20Sr(3P1)%20+%20HF&rft.jtitle=The%20journal%20of%20physical%20chemistry.%20A,%20Molecules,%20spectroscopy,%20kinetics,%20environment,%20&%20general%20theory&rft.au=Teule,%20J.%20M&rft.date=1998-11-19&rft.volume=102&rft.issue=47&rft.spage=9482&rft.epage=9488&rft.pages=9482-9488&rft.issn=1089-5639&rft.eissn=1520-5215&rft_id=info:doi/10.1021/jp981993e&rft_dat=%3Cistex_cross%3Eark_67375_TPS_K3G8T0X0_9%3C/istex_cross%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_id=info:pmid/&rfr_iscdi=true