Isomorphic Substitution and Postsynthesis Incorporation of Zirconium into MCM-48 Mesoporous Silica

We describe the introduction of zirconium metal centers into the cubic phase of mesoporous silica. Two methods of zirconium incorporation were compared consisting of hydrothermal Si/Zr coprecipitation and postsynthesis functionalization of surface silanols with zirconium propoxide. Nitrogen sorption...

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Veröffentlicht in:The journal of physical chemistry. B 1999-03, Vol.103 (12), p.2037-2041
Hauptverfasser: Morey, Mark S, Stucky, Galen D, Schwarz, Stephan, Fröba, Michael
Format: Artikel
Sprache:eng
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