Mobility and Clustering of Rh and Ru in Zeolite. Experiment and Theory

Ruthenium and rhodium have been atomically dispersed on Na zeolite as shown by the infrared spectra of RhI(CO)2 and RuI(CO)2 produced upon reduction in a CO atmosphere. Formation of adsorbed CO bridging two Rh(I) surface atoms upon partial removal of adsorbed CO indicates some Rh(I) species can occu...

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Veröffentlicht in:The journal of physical chemistry. B 1998-12, Vol.102 (50), p.10112-10116
Hauptverfasser: Conners, Laura, Hollis, Tammy, Johnson, Dale A, Blyholder, George
Format: Artikel
Sprache:eng
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