Flux−Force Formalism for Charge Transport Dynamics in Supramolecular Structures. 2. Diffusivity and Electroneutrality Coupling Effects

The conductance and transport number expressions are derived for the ion-involved electron-hopping (IIEH) mechanism taking into account the ion pairing between fixed redox ions and the mobile electroinactive counterions. Under the steady-state condition, the effects of ion pairing, the ratio of diff...

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Veröffentlicht in:The journal of physical chemistry. B 1998-03, Vol.102 (12), p.2138-2148
Hauptverfasser: Denny, R. Aldrin, Sangaranarayanan, M. V
Format: Artikel
Sprache:eng
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