Spectroscopic and Electrochemical Probes of Electronic Coupling in Some Cyanide-Bridged Transition Metal Donor/Acceptor Complexes

The effects of donor−acceptor (D/A) electronic coupling, H DA, on the spectroscopic and electrochemical properties of several series of CN--bridged transition metal complexes have been examined. The complexes employed were formed by ruthenation of M(L)(CN)2 n + parent complexes (for n = 0, M = Ru(II...

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Veröffentlicht in:	The journal of physical chemistry. A, Molecules, spectroscopy, kinetics, environment, & general theory Molecules, spectroscopy, kinetics, environment, & general theory, 1997-11, Vol.101 (45), p.8441-8459
Hauptverfasser:	Watzky, Murielle A, Macatangay, Ariel V, Van Camp, Richard A, Mazzetto, Selma E, Song, Xiaoqing, Endicott, John F, Buranda, Tione
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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