Electrochemical and Spectroscopic Investigation of the Influence of Acid−Base Chemistry on the Redox Properties of 2,5-Dimercapto-1,3,4-thiadiazole

The UV−vis spectroscopy and cyclic voltammetry of 2,5-dimercapto-1,3,4-thiadiazole (DMcT) were studied in the absence and presence of pyridine (Py) or triethylamine (TEA) in acetonitrile solutions in order to examine the influence of acid−base processes on the redox behavior of DMcT. In solutions co...

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Veröffentlicht in:The journal of physical chemistry. B 1997-04, Vol.101 (15), p.2861-2866
Hauptverfasser: Shouji, Eiichi, Yokoyama, Yasuyuki, Pope, John M, Oyama, Noboru, Buttry, Daniel A
Format: Artikel
Sprache:eng
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