Branching Ratios in Activated Systems

Branching between reaction channels in activated systems is often observed to vary with changes in the potential energy surface as Δln(k 1/k 2) ∝ Δ(Δ − Δ ). RRKM calculations demonstrate that in many, but not all, cases the log−linear relationship accurately describes branching in nonthermal distrib...

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Veröffentlicht in:The journal of physical chemistry. A, Molecules, spectroscopy, kinetics, environment, & general theory Molecules, spectroscopy, kinetics, environment, & general theory, 1997-01, Vol.101 (1), p.19-24
Hauptverfasser: Craig, Stephen L, Zhong, Meili, Choo, Bryan, Brauman, John I
Format: Artikel
Sprache:eng
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