Multiphoton Ionization of Liquid Water with 3.0−5.0 eV Photons

We report a picosecond laser study of the transient absorption of hydrated electrons generated by the 3−5 eV multiphoton ionization of liquid water. The geminate kinetics indicate that eaq - is produced by at least three different mechanisms over this energy range. Power dependence of the signal amp...

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Veröffentlicht in:	Journal of Physical Chemistry 1996-11, Vol.100 (45), p.17940-17949
Hauptverfasser:	Crowell, Robert A, Bartels, David M
Format:	Artikel
Sprache:	eng
Schlagworte:	40 CHEMISTRY ABSORPTION SPECTRA ATOMS BORN-OPPENHEIMER APPROXIMATION COMPUTERIZED SIMULATION DECAY DIFFUSION ENGINEERING NOT INCLUDED IN OTHER CATEGORIES EXCITED STATES HYDROGEN HYDROXYL RADICALS LASER SPECTROSCOPY MATHEMATICS, COMPUTERS, INFORMATION SCIENCE, MANAGEMENT, LAW, MISCELLANEOUS PHOTOIONIZATION PROBABILITY RECOMBINATION ULTRAVIOLET SPECTRA WATER
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