High-Frequency Electron Paramagnetic Resonance Spectroscopy of the Apogalactose Oxidase Radical

The activated form of galactose oxidase from the fungus Dactylium dendroides contains a single divalent copper ion which is antiferromagnetically coupled to a protein-based free radical. Chemical oxidation of the apoenzyme generates the free radical which is localized on a covalently cross-linked ty...

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Veröffentlicht in:	Journal of physical chemistry (1952) 1996-10, Vol.100 (41), p.16739-16748
Hauptverfasser:	Gerfen, Gary J, Bellew, Brendan F, Griffin, Robert G, Singel, David J, Ekberg, Christopher A, Whittaker, James W
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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