Solubilities of Uranium(IV) Dioxide in Magnesium Chloride, Calcium Chloride, and Aluminum Chloride Melts:  A Comparative Study

Solubilities of Uranium(IV) Dioxide in Magnesium Chloride, Calcium Chloride, and Aluminum Chloride Melts:  A Comparative Study

High-temperature near-IR absorption spectroscopy was used to study the dissolution of UO2 in molten MgCl2, CaCl2, and AlCl3 melts. The study reveals that UO2 is most soluble in molten AlCl3, followed by the melt of MgCl2. The solubility of UO2 in molten CaCl2 is too small to be measured with optical...

Ausführliche Beschreibung

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:Journal of Physical Chemistry 1996-01, Vol.100 (1), p.220-223
Hauptverfasser: Dai, Sheng, Toth, L. M, Del Cul, G. D, Metcalf, D. H
Format: Artikel
Sprache:eng
Schlagworte:
05 NUCLEAR FUELS
40 CHEMISTRY
ABSORPTION SPECTRA
ALUMINIUM CHLORIDES
CALCIUM CHLORIDES
DISSOLUTION
MAGNESIUM CHLORIDES
MATHEMATICAL MODELS
NUCLEAR FUELS
PROCESSING
SOLUBILITY
THERMODYNAMIC CYCLES
URANIUM DIOXIDE
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
container_end_page 223
container_issue 1
container_start_page 220
container_title Journal of Physical Chemistry
container_volume 100
creator Dai, Sheng
Toth, L. M
Del Cul, G. D
Metcalf, D. H
description High-temperature near-IR absorption spectroscopy was used to study the dissolution of UO2 in molten MgCl2, CaCl2, and AlCl3 melts. The study reveals that UO2 is most soluble in molten AlCl3, followed by the melt of MgCl2. The solubility of UO2 in molten CaCl2 is too small to be measured with optical spectroscopy. This strong dependence of the solubility on the cations of the melts was rationalized by the use of the Flood−Forland−Grjotheim thermodynamic cycle.
doi_str_mv 10.1021/jp952100a
format Article
fullrecord <record><control><sourceid>acs_osti_</sourceid><recordid>TN_cdi_crossref_primary_10_1021_jp952100a</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>c495007697</sourcerecordid><originalsourceid>FETCH-LOGICAL-a387t-554fe38de15de6554db85a5c3ab3d96bef0dff398b409dcc8f7eee2e31068aae3</originalsourceid><addsrcrecordid>eNptkF1r2zAUhkVZoVm7i_0D9WLQwrxKliXbvQvumgVS2pF-XApZOm6VOVaQ5JLc5XZ_s79kHimlg10dznMeXjgvQp8p-UZJSs8Wq5KnlBC1h0aUZzTheUY-oBEhaZowwbMD9DGEBSGEMkZHaDt3bV_b1kYLAbsG33nV2X55Mr0_xRfWra0BbDt8pR47CMMBV0-t8wP9iivV6n-J6gwet_3Sdu8wvoI2hvOX7W88xpVbrpRX0T4DnsfebI7QfqPaAJ9e5yG6u_x-W_1IZteTaTWeJYoVeUw4zxpghQHKDYhhM3XBFddM1cyUooaGmKZhZVFnpDRaF00OACkwSkShFLBDdLzLdSFaGbSNoJ-06zrQUdJSCCYG53TnaO9C8NDIlbdL5TeSEvm3XvlW7-AmO9eGCOs3UflfUuQs5_L2Zi5_isv5Q1ZdyMngf9n5Sge5cL3vhm__k_sH0WyKkg</addsrcrecordid><sourcetype>Open Access Repository</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype></control><display><type>article</type><title>Solubilities of Uranium(IV) Dioxide in Magnesium Chloride, Calcium Chloride, and Aluminum Chloride Melts:  A Comparative Study</title><source>ACS Publications</source><creator>Dai, Sheng ; Toth, L. M ; Del Cul, G. D ; Metcalf, D. H</creator><creatorcontrib>Dai, Sheng ; Toth, L. M ; Del Cul, G. D ; Metcalf, D. H</creatorcontrib><description>High-temperature near-IR absorption spectroscopy was used to study the dissolution of UO2 in molten MgCl2, CaCl2, and AlCl3 melts. The study reveals that UO2 is most soluble in molten AlCl3, followed by the melt of MgCl2. The solubility of UO2 in molten CaCl2 is too small to be measured with optical spectroscopy. This strong dependence of the solubility on the cations of the melts was rationalized by the use of the Flood−Forland−Grjotheim thermodynamic cycle.</description><identifier>ISSN: 0022-3654</identifier><identifier>EISSN: 1541-5740</identifier><identifier>DOI: 10.1021/jp952100a</identifier><language>eng</language><publisher>United States: American Chemical Society</publisher><subject>05 NUCLEAR FUELS ; 40 CHEMISTRY ; ABSORPTION SPECTRA ; ALUMINIUM CHLORIDES ; CALCIUM CHLORIDES ; DISSOLUTION ; MAGNESIUM CHLORIDES ; MATHEMATICAL MODELS ; NUCLEAR FUELS ; PROCESSING ; SOLUBILITY ; THERMODYNAMIC CYCLES ; URANIUM DIOXIDE</subject><ispartof>Journal of Physical Chemistry, 1996-01, Vol.100 (1), p.220-223</ispartof><rights>Copyright © 1996 American Chemical Society</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-a387t-554fe38de15de6554db85a5c3ab3d96bef0dff398b409dcc8f7eee2e31068aae3</citedby><cites>FETCH-LOGICAL-a387t-554fe38de15de6554db85a5c3ab3d96bef0dff398b409dcc8f7eee2e31068aae3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://pubs.acs.org/doi/pdf/10.1021/jp952100a$$EPDF$$P50$$Gacs$$H</linktopdf><linktohtml>$$Uhttps://pubs.acs.org/doi/10.1021/jp952100a$$EHTML$$P50$$Gacs$$H</linktohtml><link.rule.ids>314,780,784,885,2763,27075,27923,27924,56737,56787</link.rule.ids><backlink>$$Uhttps://www.osti.gov/biblio/196636$$D View this record in Osti.gov$$Hfree_for_read</backlink></links><search><creatorcontrib>Dai, Sheng</creatorcontrib><creatorcontrib>Toth, L. M</creatorcontrib><creatorcontrib>Del Cul, G. D</creatorcontrib><creatorcontrib>Metcalf, D. H</creatorcontrib><title>Solubilities of Uranium(IV) Dioxide in Magnesium Chloride, Calcium Chloride, and Aluminum Chloride Melts:  A Comparative Study</title><title>Journal of Physical Chemistry</title><addtitle>J. Phys. Chem</addtitle><description>High-temperature near-IR absorption spectroscopy was used to study the dissolution of UO2 in molten MgCl2, CaCl2, and AlCl3 melts. The study reveals that UO2 is most soluble in molten AlCl3, followed by the melt of MgCl2. The solubility of UO2 in molten CaCl2 is too small to be measured with optical spectroscopy. This strong dependence of the solubility on the cations of the melts was rationalized by the use of the Flood−Forland−Grjotheim thermodynamic cycle.</description><subject>05 NUCLEAR FUELS</subject><subject>40 CHEMISTRY</subject><subject>ABSORPTION SPECTRA</subject><subject>ALUMINIUM CHLORIDES</subject><subject>CALCIUM CHLORIDES</subject><subject>DISSOLUTION</subject><subject>MAGNESIUM CHLORIDES</subject><subject>MATHEMATICAL MODELS</subject><subject>NUCLEAR FUELS</subject><subject>PROCESSING</subject><subject>SOLUBILITY</subject><subject>THERMODYNAMIC CYCLES</subject><subject>URANIUM DIOXIDE</subject><issn>0022-3654</issn><issn>1541-5740</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>1996</creationdate><recordtype>article</recordtype><recordid>eNptkF1r2zAUhkVZoVm7i_0D9WLQwrxKliXbvQvumgVS2pF-XApZOm6VOVaQ5JLc5XZ_s79kHimlg10dznMeXjgvQp8p-UZJSs8Wq5KnlBC1h0aUZzTheUY-oBEhaZowwbMD9DGEBSGEMkZHaDt3bV_b1kYLAbsG33nV2X55Mr0_xRfWra0BbDt8pR47CMMBV0-t8wP9iivV6n-J6gwet_3Sdu8wvoI2hvOX7W88xpVbrpRX0T4DnsfebI7QfqPaAJ9e5yG6u_x-W_1IZteTaTWeJYoVeUw4zxpghQHKDYhhM3XBFddM1cyUooaGmKZhZVFnpDRaF00OACkwSkShFLBDdLzLdSFaGbSNoJ-06zrQUdJSCCYG53TnaO9C8NDIlbdL5TeSEvm3XvlW7-AmO9eGCOs3UflfUuQs5_L2Zi5_isv5Q1ZdyMngf9n5Sge5cL3vhm__k_sH0WyKkg</recordid><startdate>19960104</startdate><enddate>19960104</enddate><creator>Dai, Sheng</creator><creator>Toth, L. M</creator><creator>Del Cul, G. D</creator><creator>Metcalf, D. H</creator><general>American Chemical Society</general><scope>BSCLL</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>OTOTI</scope></search><sort><creationdate>19960104</creationdate><title>Solubilities of Uranium(IV) Dioxide in Magnesium Chloride, Calcium Chloride, and Aluminum Chloride Melts:  A Comparative Study</title><author>Dai, Sheng ; Toth, L. M ; Del Cul, G. D ; Metcalf, D. H</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-a387t-554fe38de15de6554db85a5c3ab3d96bef0dff398b409dcc8f7eee2e31068aae3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>1996</creationdate><topic>05 NUCLEAR FUELS</topic><topic>40 CHEMISTRY</topic><topic>ABSORPTION SPECTRA</topic><topic>ALUMINIUM CHLORIDES</topic><topic>CALCIUM CHLORIDES</topic><topic>DISSOLUTION</topic><topic>MAGNESIUM CHLORIDES</topic><topic>MATHEMATICAL MODELS</topic><topic>NUCLEAR FUELS</topic><topic>PROCESSING</topic><topic>SOLUBILITY</topic><topic>THERMODYNAMIC CYCLES</topic><topic>URANIUM DIOXIDE</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Dai, Sheng</creatorcontrib><creatorcontrib>Toth, L. M</creatorcontrib><creatorcontrib>Del Cul, G. D</creatorcontrib><creatorcontrib>Metcalf, D. H</creatorcontrib><collection>Istex</collection><collection>CrossRef</collection><collection>OSTI.GOV</collection><jtitle>Journal of Physical Chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Dai, Sheng</au><au>Toth, L. M</au><au>Del Cul, G. D</au><au>Metcalf, D. H</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Solubilities of Uranium(IV) Dioxide in Magnesium Chloride, Calcium Chloride, and Aluminum Chloride Melts:  A Comparative Study</atitle><jtitle>Journal of Physical Chemistry</jtitle><addtitle>J. Phys. Chem</addtitle><date>1996-01-04</date><risdate>1996</risdate><volume>100</volume><issue>1</issue><spage>220</spage><epage>223</epage><pages>220-223</pages><issn>0022-3654</issn><eissn>1541-5740</eissn><abstract>High-temperature near-IR absorption spectroscopy was used to study the dissolution of UO2 in molten MgCl2, CaCl2, and AlCl3 melts. The study reveals that UO2 is most soluble in molten AlCl3, followed by the melt of MgCl2. The solubility of UO2 in molten CaCl2 is too small to be measured with optical spectroscopy. This strong dependence of the solubility on the cations of the melts was rationalized by the use of the Flood−Forland−Grjotheim thermodynamic cycle.</abstract><cop>United States</cop><pub>American Chemical Society</pub><doi>10.1021/jp952100a</doi><tpages>4</tpages></addata></record>
fulltext fulltext
identifier ISSN: 0022-3654
ispartof Journal of Physical Chemistry, 1996-01, Vol.100 (1), p.220-223
issn 0022-3654
1541-5740
language eng
recordid cdi_crossref_primary_10_1021_jp952100a
source ACS Publications
subjects 05 NUCLEAR FUELS
40 CHEMISTRY
ABSORPTION SPECTRA
ALUMINIUM CHLORIDES
CALCIUM CHLORIDES
DISSOLUTION
MAGNESIUM CHLORIDES
MATHEMATICAL MODELS
NUCLEAR FUELS
PROCESSING
SOLUBILITY
THERMODYNAMIC CYCLES
URANIUM DIOXIDE
title Solubilities of Uranium(IV) Dioxide in Magnesium Chloride, Calcium Chloride, and Aluminum Chloride Melts:  A Comparative Study
url https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-01-12T16%3A47%3A29IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-acs_osti_&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Solubilities%20of%20Uranium(IV)%20Dioxide%20in%20Magnesium%20Chloride,%20Calcium%20Chloride,%20and%20Aluminum%20Chloride%20Melts:%E2%80%89%20A%20Comparative%20Study&rft.jtitle=Journal%20of%20Physical%20Chemistry&rft.au=Dai,%20Sheng&rft.date=1996-01-04&rft.volume=100&rft.issue=1&rft.spage=220&rft.epage=223&rft.pages=220-223&rft.issn=0022-3654&rft.eissn=1541-5740&rft_id=info:doi/10.1021/jp952100a&rft_dat=%3Cacs_osti_%3Ec495007697%3C/acs_osti_%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_id=info:pmid/&rfr_iscdi=true