Concerted Proton−Electron Transfer: Effect of Hydroxylic Additives on the Reduction of Benzophenone, 4-Cyanobenzophenone, and 4,4′-Dicyanobenzophenone

The electrochemical reduction of the title compounds proceeds in two steps in N,N-dimethylformamide. The first step is a one-electron reduction to form the anion radical of the benzophenone, a reaction which is affected by the presence of hydroxylic additives such as water, ethanol, or methanol beca...

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Veröffentlicht in:	Journal of physical chemistry. C 2009-09, Vol.113 (38), p.16686-16693
Hauptverfasser:	Wang, Shihua, Singh, Pradyumna S, Evans, Dennis H
Format:	Artikel
Sprache:	eng
Schlagworte:	C: Surfaces, Interfaces, Catalysis
Online-Zugang:	Volltext
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