A Surface Core Level Shift Study of Hydrogen-Induced Ordered Structures on Rh(110)

A Surface Core Level Shift Study of Hydrogen-Induced Ordered Structures on Rh(110)

The interaction of hydrogen with Rh(110) was studied by means of high-resolution core level photoelectron spectroscopy, in combination with temperature-programmed desorption spectroscopy, low energy electron diffraction, and scanning tunneling microscopy measurements. By exploiting the H-induced Rh3...

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Veröffentlicht in:Journal of physical chemistry. C 2008-09, Vol.112 (37), p.14475-14480
Hauptverfasser: Vesselli, Erik, Campaniello, Marco, Baraldi, Alessandro, Bianchettin, Laura, Africh, Cristina, Esch, Friedrich, Lizzit, Silvano, Comelli, Giovanni
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C: Surfaces, Interfaces, Catalysis
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container_end_page 14480
container_issue 37
container_start_page 14475
container_title Journal of physical chemistry. C
container_volume 112
creator Vesselli, Erik
Campaniello, Marco
Baraldi, Alessandro
Bianchettin, Laura
Africh, Cristina
Esch, Friedrich
Lizzit, Silvano
Comelli, Giovanni
description The interaction of hydrogen with Rh(110) was studied by means of high-resolution core level photoelectron spectroscopy, in combination with temperature-programmed desorption spectroscopy, low energy electron diffraction, and scanning tunneling microscopy measurements. By exploiting the H-induced Rh3d 5/2 surface core level shift sensitivity to the local coordination environment, we propose here new structural models for the intermediate coverage 0.67 and 1.0 ML overlayers, while we confirm the previous results for the low coverage structures at 0.33 and 0.5 ML, and for the saturation phase at 2.0 ML. Surface core level shift values are interpreted on the basis of our previous data about the hydrogen adsorption on the (100) and (111) rhodium surfaces. The proposed structural models are supported by scanning tunneling images of the surface and provide a comprehensive description of all the available experimental data.
doi_str_mv 10.1021/jp803112q
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title A Surface Core Level Shift Study of Hydrogen-Induced Ordered Structures on Rh(110)
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