Charge Transfer in Donor-Bridge-Acceptor Systems: Static Disorder, Dynamic Fluctuations, and Complex Kinetics

The influence of static and dynamic torsional disorder on the kinetics of charge transfer (CT) in donor-bridge-acceptor (D-B-A) systems has been investigated theoretically using a simple tight-binding model. In such systems, variations of the torsion angle often give rise either to static changes in...

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Veröffentlicht in:Journal of physical chemistry. C 2008-07, Vol.112 (29), p.10988-11000
Hauptverfasser: Berlin, Yuri A, Grozema, Ferdinand C, Siebbeles, Laurens D. A, Ratner, Mark A
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Sprache:eng
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