A Simple and Low-Cost Method for the Preparation of Monodisperse Hollow Silica Spheres
This paper presents a simple and low-cost method to prepare hollow silica spheres. This method is just based on a PVP-involved emulsion polymerization and subsequent sol−gel process. PVP first participated in the polymerization reaction as a stabilizer or surfactant and then played a coupling agent...
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Veröffentlicht in: | Journal of physical chemistry. C 2008-08, Vol.112 (31), p.11623-11629 |
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creator | Zou, Hua Wu, Shishan Ran, Qianping Shen, Jian |
description | This paper presents a simple and low-cost method to prepare hollow silica spheres. This method is just based on a PVP-involved emulsion polymerization and subsequent sol−gel process. PVP first participated in the polymerization reaction as a stabilizer or surfactant and then played a coupling agent role in the latter process. The polystyrene particles were dissolved subsequently or simultaneously during the sol−gel coating process to form hollow silica spheres. The influence of some parameters, such as the amount of PVP, the amount of NH4OH, and the amount of TEOS on the morphology of the hollow spheres was investigated. The parameters to control over the formation of all hollow spheres were also studied. |
doi_str_mv | 10.1021/jp800557k |
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This method is just based on a PVP-involved emulsion polymerization and subsequent sol−gel process. PVP first participated in the polymerization reaction as a stabilizer or surfactant and then played a coupling agent role in the latter process. The polystyrene particles were dissolved subsequently or simultaneously during the sol−gel coating process to form hollow silica spheres. The influence of some parameters, such as the amount of PVP, the amount of NH4OH, and the amount of TEOS on the morphology of the hollow spheres was investigated. The parameters to control over the formation of all hollow spheres were also studied.</description><identifier>ISSN: 1932-7447</identifier><identifier>EISSN: 1932-7455</identifier><identifier>DOI: 10.1021/jp800557k</identifier><language>eng</language><publisher>American Chemical Society</publisher><subject>C: Nanops and Nanostructures</subject><ispartof>Journal of physical chemistry. 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C</title><addtitle>J. Phys. Chem. C</addtitle><description>This paper presents a simple and low-cost method to prepare hollow silica spheres. This method is just based on a PVP-involved emulsion polymerization and subsequent sol−gel process. PVP first participated in the polymerization reaction as a stabilizer or surfactant and then played a coupling agent role in the latter process. The polystyrene particles were dissolved subsequently or simultaneously during the sol−gel coating process to form hollow silica spheres. The influence of some parameters, such as the amount of PVP, the amount of NH4OH, and the amount of TEOS on the morphology of the hollow spheres was investigated. 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C</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Zou, Hua</au><au>Wu, Shishan</au><au>Ran, Qianping</au><au>Shen, Jian</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>A Simple and Low-Cost Method for the Preparation of Monodisperse Hollow Silica Spheres</atitle><jtitle>Journal of physical chemistry. C</jtitle><addtitle>J. Phys. Chem. C</addtitle><date>2008-08-07</date><risdate>2008</risdate><volume>112</volume><issue>31</issue><spage>11623</spage><epage>11629</epage><pages>11623-11629</pages><issn>1932-7447</issn><eissn>1932-7455</eissn><abstract>This paper presents a simple and low-cost method to prepare hollow silica spheres. This method is just based on a PVP-involved emulsion polymerization and subsequent sol−gel process. PVP first participated in the polymerization reaction as a stabilizer or surfactant and then played a coupling agent role in the latter process. The polystyrene particles were dissolved subsequently or simultaneously during the sol−gel coating process to form hollow silica spheres. The influence of some parameters, such as the amount of PVP, the amount of NH4OH, and the amount of TEOS on the morphology of the hollow spheres was investigated. The parameters to control over the formation of all hollow spheres were also studied.</abstract><pub>American Chemical Society</pub><doi>10.1021/jp800557k</doi><tpages>7</tpages></addata></record> |
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subjects | C: Nanops and Nanostructures |
title | A Simple and Low-Cost Method for the Preparation of Monodisperse Hollow Silica Spheres |
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