Coverage-Dependent Interactions at the Organics–Metal Interface: Quinonoid Zwitterions on Au(111)

The large intrinsic electric dipole of about 10 D of a p-benzoquinonemonoimine compound from the class of N-alkyldiaminoresorcinone (or 4,6-bisdialkylaminobenzene-1,3-diones, i.e., C6H2(··· NHR)2(··· O)2, where R = H) zwitterions is reduced considerably upon adsorption on Au(111) substrates. Scannin...

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Veröffentlicht in:	Journal of physical chemistry. C 2013-08, Vol.117 (32), p.16406-16415
Hauptverfasser:	Simpson, Scott, Kunkel, Donna A, Hooper, James, Nitz, Justin, Dowben, Peter A, Routaboul, Lucie, Braunstein, Pierre, Doudin, Bernard, Enders, Axel, Zurek, Eva
Format:	Artikel
Sprache:	eng
Schlagworte:	Condensed matter: electronic structure, electrical, magnetic, and optical properties Condensed matter: structure, mechanical and thermal properties Electron, ion, and scanning probe microscopy Electronic structure and electrical properties of surfaces, interfaces, thin films and low-dimensional structures Electronic transport phenomena in thin films and low-dimensional structures Exact sciences and technology Physics Solid surfaces and solid-solid interfaces Structure and morphology thickness Structure of solids and liquids crystallography Surface structure and topography Surfaces and interfaces thin films and whiskers (structure and nonelectronic properties) Thin film structure and morphology
Online-Zugang:	Volltext
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