Effect of Surface Acidic and Basic Properties of the Supported Nickel Catalysts on the Hydrogenation of Pyridine to Piperidine

Ni/Al2O3, Ni/MgAlO, and Ni/MgO catalysts were studied for the hydrogenation of pyridine to piperidine. Microcalorimetric adsorption and infrared spectroscopy were used to study the adsorption of CO, H2, pyridine, and piperidine on the catalysts. It was found that the basic support (MgO) increased th...

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Veröffentlicht in:Journal of physical chemistry. C 2013-05, Vol.117 (20), p.10573-10580
Hauptverfasser: Zhao, Jie, Chen, Hui, Xu, Jun, Shen, Jianyi
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Sprache:eng
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