Reaction Mechanism of Aromatic Ring Amination of Benzene and Substituted Benzenes by Aqueous Ammonia over Platinum-Loaded Titanium Oxide Photocatalyst

The reaction mechanism of photocatalytic aromatic ring amination of benzene and the derivatives with aqueous ammonia was clarified by some reaction experiments and electron spin resonance spectroscopy as follows: a platinum-loaded titanium oxide photocatalyst oxidizes an ammonia to form an amide rad...

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Veröffentlicht in:Journal of physical chemistry. C 2013-05, Vol.117 (21), p.11047-11058
Hauptverfasser: Yuzawa, Hayato, Kumagai, Jun, Yoshida, Hisao
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Sprache:eng
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