Detection of Surface Chirality by Electrolyte Electroreflectance Rotational Anisotropy

Detection of Surface Chirality by Electrolyte Electroreflectance Rotational Anisotropy

The ability of electrolyte electroreflectance rotational anisotropy (EERRA) to detect surface chirality is demonstrated by measuring the EERRA of Au(11 7 5) L and Au(11 7 5) D . Chiral surfaces do not contain any symmetry planes, and, hence, in their case χ xy ≠ χ yx . Accordingly, the EERRA pattern...

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Veröffentlicht in:Journal of physical chemistry. C 2007-10, Vol.111 (39), p.14290-14292
Hauptverfasser: Cuesta, Ángel, Borrás, Carlos
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container_title Journal of physical chemistry. C
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creator Cuesta, Ángel
Borrás, Carlos
description The ability of electrolyte electroreflectance rotational anisotropy (EERRA) to detect surface chirality is demonstrated by measuring the EERRA of Au(11 7 5) L and Au(11 7 5) D . Chiral surfaces do not contain any symmetry planes, and, hence, in their case χ xy ≠ χ yx . Accordingly, the EERRA patterns, like the surfaces they originate from, do not contain any symmetry planes, and are, hence, chiral, the pattern corresponding to Au(11 7 5) L being the mirror image of the pattern corresponding to Au(11 7 5) D .
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title Detection of Surface Chirality by Electrolyte Electroreflectance Rotational Anisotropy
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