Two-Dimensional Self-Organization of CdS Ultra Thin Films by Confined Electrochemical Atomic Layer Epitaxy Growth
We present a method that uses patterned self-assembled monolayers (SAMs) of alkanethiolates on silver as templates to fabricate ordered two-dimensional arrays of solid CdS nanoclusters. The CdS is grown by electrochemical atomic layer epitaxy inside sub-micrometric stripes of hexadecanthiol SAM fabr...
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Veröffentlicht in: | Journal of physical chemistry. C 2007-01, Vol.111 (3), p.1061-1064 |
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container_title | Journal of physical chemistry. C |
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creator | Cavallini, Massimiliano Facchini, Massimo Albonetti, Cristiano Biscarini, Fabio Innocenti, Massimo Loglio, Francesca Salvietti, Emanuele Pezzatini, Giovanni Foresti, Maria Luisa |
description | We present a method that uses patterned self-assembled monolayers (SAMs) of alkanethiolates on silver as templates to fabricate ordered two-dimensional arrays of solid CdS nanoclusters. The CdS is grown by electrochemical atomic layer epitaxy inside sub-micrometric stripes of hexadecanthiol SAM fabricated by microcontact printing. CdS ultrathin films grow and self-organize into an ordered pattern of nanoclusters. This pattern exhibits both lithographically imposed ordered structures and a self-affine structure along the direction perpendicular to the stripes. On the contrary, along the direction parallel to the stripes no spatial correlation among the clusters has ever been observed. |
doi_str_mv | 10.1021/jp0668908 |
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title | Two-Dimensional Self-Organization of CdS Ultra Thin Films by Confined Electrochemical Atomic Layer Epitaxy Growth |
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