The Shortest Symmetrical O−H···O Hydrogen Bond Has a Low-Barrier Double-Well Potential

The strong hydrogen bond, in which a hydrogen atom is centered between two electronegative atoms in a single minimum potential has been widely discussed but rarely definitively observed. The compound 4-cyano-2,2,6,6-tetramethyl-3,5-heptanedione has the shortest symmetrical O−H···O hydrogen bond yet...

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Veröffentlicht in:	Journal of Physical Chemistry B: Materials, Surfaces, Interfaces, amp Biophysical Surfaces, Interfaces, amp Biophysical, 2004-06, Vol.108 (22), p.6922-6926
Hauptverfasser:	Belot, John A, Clark, Joanna, Cowan, John A, Harbison, Gerard S, Kolesnikov, Alexander I, Kye, Young-Sik, Schultz, Arthur J, Silvernail, Carter, Zhao, Xingang
Format:	Artikel
Sprache:	eng
Schlagworte:	CHEMICAL BONDS HYDROGEN INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY INTENSE PULSED NEUTRON SOURCE WATER
Online-Zugang:	Volltext
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