Effect of Fractional Fluorination on the Properties of ATRP Surface-Initiated Poly(hydroxyethyl methacrylate) Films

Acylation of a surface-initiated poly(hydroxyethyl methacrylate) (PHEMA) film with a perfluoroalkyl acid chloride (C7F15COCl) results in a highly blocking film with fluorocarbon side groups that orient at the air−film interface to produce an ultralow-energy surface. The kinetics of the acylation ste...

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Veröffentlicht in:	The journal of physical chemistry. B 2004-07, Vol.108 (28), p.9787-9794
Hauptverfasser:	Bantz, Mayker R, Brantley, Eric L, Weinstein, Randy D, Moriarty, Jeffrey, Jennings, G. Kane
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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