Electronic Interaction Anisotropy between Atoms in Arbitrary Angular Momentum States

A general tensorial expansion for the interaction potential between two atoms in arbitrary angular momentum states is derived and the relations between the expansion coefficients and the Born−Oppenheimer potentials of the diatomic molecule are obtained. It is demonstrated that a complete expansion o...

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Veröffentlicht in:The journal of physical chemistry. A, Molecules, spectroscopy, kinetics, environment, & general theory Molecules, spectroscopy, kinetics, environment, & general theory, 2004-10, Vol.108 (41), p.8941-8948
Hauptverfasser: Krems, R. V, Groenenboom, G. C, Dalgarno, A
Format: Artikel
Sprache:eng
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