Thermal and Photolytic Reactions of Group 12 Metal Atoms in HCl-Doped Argon Matrixes:  Formation and Characterization of the Hydride Species HMCl (M = Zn, Cd, or Hg)

IR and UV−vis spectroscopic measurements have been used to chart the thermal and photolytic reactions occurring in HCl-doped Ar matrixes containing Zn, Cd, or Hg atoms (M). Following the formation of a loosely bound metal atom adduct M···HCl, the primary reaction induced by UV irradiation (200 ≤ λ ≤...

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Veröffentlicht in:	The journal of physical chemistry. A, Molecules, spectroscopy, kinetics, environment, & general theory Molecules, spectroscopy, kinetics, environment, & general theory, 2004-11, Vol.108 (44), p.9500-9509
Hauptverfasser:	Macrae, Victoria A, Green, Jennifer C, Greene, Tim M, Downs, Antony J
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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