Infrared Multiphoton Si Isotope Selective Dissociation of Phenyltrifluorosilane under Free Electron Laser Irradiation
We have used free electron laser (FEL) at the IR FEL Research Center, Research Institute for Science and Technology, Tokyo University of Science, Japan. The multiphoton absorption of infrared radiation induced dissociation of phenyltrifluorosilane (PhSiF3) in a batch reactor. End product analysis fr...
Gespeichert in:
| Veröffentlicht in: | The journal of physical chemistry. A, Molecules, spectroscopy, kinetics, environment, & general theory Molecules, spectroscopy, kinetics, environment, & general theory, 2003-11, Vol.107 (44), p.9362-9367 |
|---|---|
| Hauptverfasser: | , , , , , , , |
| Format: | Artikel |
| Sprache: | eng |
| Online-Zugang: | Volltext |
| Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
| container_end_page | 9367 |
|---|---|
| container_issue | 44 |
| container_start_page | 9362 |
| container_title | The journal of physical chemistry. A, Molecules, spectroscopy, kinetics, environment, & general theory |
| container_volume | 107 |
| creator | Chernyshev, Andrei V Nomaru, Keiji Petrov, Alexander K Chesnokov, Evgeni N Gorelik, Sergey R Kuibida, Leonid V Akberdin, Rustam R Kuroda, Haruo |
| description | We have used free electron laser (FEL) at the IR FEL Research Center, Research Institute for Science and Technology, Tokyo University of Science, Japan. The multiphoton absorption of infrared radiation induced dissociation of phenyltrifluorosilane (PhSiF3) in a batch reactor. End product analysis from IR MPD of neat PhSiF3 and the mixture of PhSiF3 and Br2 shows that the main dissociation channels are (1) the elimination of SiF3 and (2) the elimination of H. Silicon isotopes have been enriched under the FEL irradiation of neat PhSiF3 at 961 cm-1 (abundance of 30Si in PhSiF3 was increased from 3.10 ± 0.03% to 12.3 ± 0.1%) and 925 cm-1 (abundance of 28Si in PhSiF3 was increased from 92.2 ± 0.9% to 96.5 ± 0.9%). |
| doi_str_mv | 10.1021/jp034214p |
| format | Article |
| fullrecord | <record><control><sourceid>acs_cross</sourceid><recordid>TN_cdi_crossref_primary_10_1021_jp034214p</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>b066078221</sourcerecordid><originalsourceid>FETCH-LOGICAL-a295t-e55e454bc7dafa43ac9e7ff8dd0cd1c85f961a34bf89f9c3cbce63f96c426af33</originalsourceid><addsrcrecordid>eNptkDFPwzAQhS0EEqUw8A-8MDAE7NhO4hGVtkQqoqJltlznrLqEJLITRP89roo6Md3T0_ee7g6hW0oeKEnp464jjKeUd2doREVKEpFScR41KWQiMiYv0VUIO0IIZSkfoaFsrNceKvw61L3rtm3fNnjlcBmi6gCvoAbTu2_Azy6E1jjdu0i0Fi-30Ozr3jtbD61vg6t1A3hoKvB45gHw9JD0EV7oEL3Se10d49fowuo6wM3fHKOP2XQ9eUkWb_Ny8rRIdCpFn4AQwAXfmLzSVnOmjYTc2qKqiKmoKYSVGdWMb2whrTTMbAxkLJqGp5m2jI3R_bHXxP2CB6s677603ytK1OFf6vSvyCZH1oUefk6g9p8qy1ku1Hq5UnIuc_6-popE_u7IaxPUrh18Ey_5p_cXBbd8vQ</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype></control><display><type>article</type><title>Infrared Multiphoton Si Isotope Selective Dissociation of Phenyltrifluorosilane under Free Electron Laser Irradiation</title><source>ACS Publications</source><creator>Chernyshev, Andrei V ; Nomaru, Keiji ; Petrov, Alexander K ; Chesnokov, Evgeni N ; Gorelik, Sergey R ; Kuibida, Leonid V ; Akberdin, Rustam R ; Kuroda, Haruo</creator><creatorcontrib>Chernyshev, Andrei V ; Nomaru, Keiji ; Petrov, Alexander K ; Chesnokov, Evgeni N ; Gorelik, Sergey R ; Kuibida, Leonid V ; Akberdin, Rustam R ; Kuroda, Haruo</creatorcontrib><description>We have used free electron laser (FEL) at the IR FEL Research Center, Research Institute for Science and Technology, Tokyo University of Science, Japan. The multiphoton absorption of infrared radiation induced dissociation of phenyltrifluorosilane (PhSiF3) in a batch reactor. End product analysis from IR MPD of neat PhSiF3 and the mixture of PhSiF3 and Br2 shows that the main dissociation channels are (1) the elimination of SiF3 and (2) the elimination of H. Silicon isotopes have been enriched under the FEL irradiation of neat PhSiF3 at 961 cm-1 (abundance of 30Si in PhSiF3 was increased from 3.10 ± 0.03% to 12.3 ± 0.1%) and 925 cm-1 (abundance of 28Si in PhSiF3 was increased from 92.2 ± 0.9% to 96.5 ± 0.9%).</description><identifier>ISSN: 1089-5639</identifier><identifier>EISSN: 1520-5215</identifier><identifier>DOI: 10.1021/jp034214p</identifier><language>eng</language><publisher>American Chemical Society</publisher><ispartof>The journal of physical chemistry. A, Molecules, spectroscopy, kinetics, environment, & general theory, 2003-11, Vol.107 (44), p.9362-9367</ispartof><rights>Copyright © 2003 American Chemical Society</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-a295t-e55e454bc7dafa43ac9e7ff8dd0cd1c85f961a34bf89f9c3cbce63f96c426af33</citedby><cites>FETCH-LOGICAL-a295t-e55e454bc7dafa43ac9e7ff8dd0cd1c85f961a34bf89f9c3cbce63f96c426af33</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://pubs.acs.org/doi/pdf/10.1021/jp034214p$$EPDF$$P50$$Gacs$$H</linktopdf><linktohtml>$$Uhttps://pubs.acs.org/doi/10.1021/jp034214p$$EHTML$$P50$$Gacs$$H</linktohtml><link.rule.ids>314,776,780,2752,27053,27901,27902,56713,56763</link.rule.ids></links><search><creatorcontrib>Chernyshev, Andrei V</creatorcontrib><creatorcontrib>Nomaru, Keiji</creatorcontrib><creatorcontrib>Petrov, Alexander K</creatorcontrib><creatorcontrib>Chesnokov, Evgeni N</creatorcontrib><creatorcontrib>Gorelik, Sergey R</creatorcontrib><creatorcontrib>Kuibida, Leonid V</creatorcontrib><creatorcontrib>Akberdin, Rustam R</creatorcontrib><creatorcontrib>Kuroda, Haruo</creatorcontrib><title>Infrared Multiphoton Si Isotope Selective Dissociation of Phenyltrifluorosilane under Free Electron Laser Irradiation</title><title>The journal of physical chemistry. A, Molecules, spectroscopy, kinetics, environment, & general theory</title><addtitle>J. Phys. Chem. A</addtitle><description>We have used free electron laser (FEL) at the IR FEL Research Center, Research Institute for Science and Technology, Tokyo University of Science, Japan. The multiphoton absorption of infrared radiation induced dissociation of phenyltrifluorosilane (PhSiF3) in a batch reactor. End product analysis from IR MPD of neat PhSiF3 and the mixture of PhSiF3 and Br2 shows that the main dissociation channels are (1) the elimination of SiF3 and (2) the elimination of H. Silicon isotopes have been enriched under the FEL irradiation of neat PhSiF3 at 961 cm-1 (abundance of 30Si in PhSiF3 was increased from 3.10 ± 0.03% to 12.3 ± 0.1%) and 925 cm-1 (abundance of 28Si in PhSiF3 was increased from 92.2 ± 0.9% to 96.5 ± 0.9%).</description><issn>1089-5639</issn><issn>1520-5215</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2003</creationdate><recordtype>article</recordtype><recordid>eNptkDFPwzAQhS0EEqUw8A-8MDAE7NhO4hGVtkQqoqJltlznrLqEJLITRP89roo6Md3T0_ee7g6hW0oeKEnp464jjKeUd2doREVKEpFScR41KWQiMiYv0VUIO0IIZSkfoaFsrNceKvw61L3rtm3fNnjlcBmi6gCvoAbTu2_Azy6E1jjdu0i0Fi-30Ozr3jtbD61vg6t1A3hoKvB45gHw9JD0EV7oEL3Se10d49fowuo6wM3fHKOP2XQ9eUkWb_Ny8rRIdCpFn4AQwAXfmLzSVnOmjYTc2qKqiKmoKYSVGdWMb2whrTTMbAxkLJqGp5m2jI3R_bHXxP2CB6s677603ytK1OFf6vSvyCZH1oUefk6g9p8qy1ku1Hq5UnIuc_6-popE_u7IaxPUrh18Ey_5p_cXBbd8vQ</recordid><startdate>20031106</startdate><enddate>20031106</enddate><creator>Chernyshev, Andrei V</creator><creator>Nomaru, Keiji</creator><creator>Petrov, Alexander K</creator><creator>Chesnokov, Evgeni N</creator><creator>Gorelik, Sergey R</creator><creator>Kuibida, Leonid V</creator><creator>Akberdin, Rustam R</creator><creator>Kuroda, Haruo</creator><general>American Chemical Society</general><scope>BSCLL</scope><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>20031106</creationdate><title>Infrared Multiphoton Si Isotope Selective Dissociation of Phenyltrifluorosilane under Free Electron Laser Irradiation</title><author>Chernyshev, Andrei V ; Nomaru, Keiji ; Petrov, Alexander K ; Chesnokov, Evgeni N ; Gorelik, Sergey R ; Kuibida, Leonid V ; Akberdin, Rustam R ; Kuroda, Haruo</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-a295t-e55e454bc7dafa43ac9e7ff8dd0cd1c85f961a34bf89f9c3cbce63f96c426af33</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2003</creationdate><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Chernyshev, Andrei V</creatorcontrib><creatorcontrib>Nomaru, Keiji</creatorcontrib><creatorcontrib>Petrov, Alexander K</creatorcontrib><creatorcontrib>Chesnokov, Evgeni N</creatorcontrib><creatorcontrib>Gorelik, Sergey R</creatorcontrib><creatorcontrib>Kuibida, Leonid V</creatorcontrib><creatorcontrib>Akberdin, Rustam R</creatorcontrib><creatorcontrib>Kuroda, Haruo</creatorcontrib><collection>Istex</collection><collection>CrossRef</collection><jtitle>The journal of physical chemistry. A, Molecules, spectroscopy, kinetics, environment, & general theory</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Chernyshev, Andrei V</au><au>Nomaru, Keiji</au><au>Petrov, Alexander K</au><au>Chesnokov, Evgeni N</au><au>Gorelik, Sergey R</au><au>Kuibida, Leonid V</au><au>Akberdin, Rustam R</au><au>Kuroda, Haruo</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Infrared Multiphoton Si Isotope Selective Dissociation of Phenyltrifluorosilane under Free Electron Laser Irradiation</atitle><jtitle>The journal of physical chemistry. A, Molecules, spectroscopy, kinetics, environment, & general theory</jtitle><addtitle>J. Phys. Chem. A</addtitle><date>2003-11-06</date><risdate>2003</risdate><volume>107</volume><issue>44</issue><spage>9362</spage><epage>9367</epage><pages>9362-9367</pages><issn>1089-5639</issn><eissn>1520-5215</eissn><abstract>We have used free electron laser (FEL) at the IR FEL Research Center, Research Institute for Science and Technology, Tokyo University of Science, Japan. The multiphoton absorption of infrared radiation induced dissociation of phenyltrifluorosilane (PhSiF3) in a batch reactor. End product analysis from IR MPD of neat PhSiF3 and the mixture of PhSiF3 and Br2 shows that the main dissociation channels are (1) the elimination of SiF3 and (2) the elimination of H. Silicon isotopes have been enriched under the FEL irradiation of neat PhSiF3 at 961 cm-1 (abundance of 30Si in PhSiF3 was increased from 3.10 ± 0.03% to 12.3 ± 0.1%) and 925 cm-1 (abundance of 28Si in PhSiF3 was increased from 92.2 ± 0.9% to 96.5 ± 0.9%).</abstract><pub>American Chemical Society</pub><doi>10.1021/jp034214p</doi><tpages>6</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 1089-5639 |
| ispartof | The journal of physical chemistry. A, Molecules, spectroscopy, kinetics, environment, & general theory, 2003-11, Vol.107 (44), p.9362-9367 |
| issn | 1089-5639 1520-5215 |
| language | eng |
| recordid | cdi_crossref_primary_10_1021_jp034214p |
| source | ACS Publications |
| title | Infrared Multiphoton Si Isotope Selective Dissociation of Phenyltrifluorosilane under Free Electron Laser Irradiation |
| url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-02-16T10%3A53%3A29IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-acs_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Infrared%20Multiphoton%20Si%20Isotope%20Selective%20Dissociation%20of%20Phenyltrifluorosilane%20under%20Free%20Electron%20Laser%20Irradiation&rft.jtitle=The%20journal%20of%20physical%20chemistry.%20A,%20Molecules,%20spectroscopy,%20kinetics,%20environment,%20&%20general%20theory&rft.au=Chernyshev,%20Andrei%20V&rft.date=2003-11-06&rft.volume=107&rft.issue=44&rft.spage=9362&rft.epage=9367&rft.pages=9362-9367&rft.issn=1089-5639&rft.eissn=1520-5215&rft_id=info:doi/10.1021/jp034214p&rft_dat=%3Cacs_cross%3Eb066078221%3C/acs_cross%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_id=info:pmid/&rfr_iscdi=true |