Spectroscopic, Kinetic, and Structural Properties of Rotamers of the 2-Vinylpyridinium Ylide of Phenylchlorocarbene

The analysis of the time-resolved UV−vis absorption spectra of the 2-vinylpyridinium ylide of phenylchlorocarbene, measured by laser-flash photolysis, indicates the existence of two rotamers of this species. The absorption spectrum, rise time, and decay time of each rotamer were determined by a glob...

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Veröffentlicht in:	The journal of physical chemistry. A, Molecules, spectroscopy, kinetics, environment, & general theory Molecules, spectroscopy, kinetics, environment, & general theory, 2004-02, Vol.108 (7), p.1312-1318
Hauptverfasser:	Bonneau, Roland, Collado, Daniel, Dalibart, Michel, Liu, Michael T. H
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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