Structure and Proton Reactivity of the Semiquinone Anion and Dianion of Biphenol in Water

Whether the redox intermediate state of 4,4‘-biphenol in water, C12H8O2 -•, has a planar or staggered molecular geometry twisted about the inter-ring bond has been examined using time-resolved resonance Raman spectroscopy and electronic structure computation. Hydrogen-bonding effects on the p,p‘-bip...

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Veröffentlicht in:	The journal of physical chemistry. A, Molecules, spectroscopy, kinetics, environment, & general theory Molecules, spectroscopy, kinetics, environment, & general theory, 2002-09, Vol.106 (38), p.8908-8916
Hauptverfasser:	Tripathi, G. N. R, Chipman, Daniel M
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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