Medium Dependence of Intramolecular Vibrational Modes Coupled to MLCT Transitions in Metal Polypyridyl Complexes

The temperature and solvent dependent emission spectra of fac-[(bpy)Re(CO)3(4-Etpy)]PF6 were recorded in 4:1 (v:v) EtOH−MeOH and CH2Cl2−MeOH mixtures (bpy = 2,2‘-bipyridine; 4-Etpy = 4-ethylpyridine). The temperature-dependent emission of [Ru(bpy)3](PF6)2 and the emission spectra of [(bpy)2Ru(bpyc-N...

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Veröffentlicht in:	The journal of physical chemistry. A, Molecules, spectroscopy, kinetics, environment, & general theory Molecules, spectroscopy, kinetics, environment, & general theory, 2002-06, Vol.106 (24), p.5768-5778
Hauptverfasser:	Kestell, John D, Williams, Zachary L, Stultz, Laura K, Claude, Juan Pablo
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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