The Redox Chemistry of 4-Benzoyl-N-methylpyridinium Cations in Acetonitrile with and without Proton Donors:  The Role of Hydrogen Bonding

In anhydrous CH3CN, 4-benzoyl-N-methylpyridinium cations undergo two reversible, well-separated (ΔE 1/2 ∼ 0.6 V) one-electron reductions in analogy to quinones and viologens. If the solvent contains weak protic acids, such as water or alcohols, the first cyclic voltammetric wave remains unaffected w...

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Veröffentlicht in:	The journal of physical chemistry. B 2001-05, Vol.105 (17), p.3663-3674
Hauptverfasser:	Leventis, Nicholas, Elder, Ian A, Gao, Xuerong, Bohannan, Eric W, Sotiriou-Leventis, Chariklia, Rawashdeh, Abdel Monem M, Overschmidt, Travis J, Gaston, Kimberly R
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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