Unified Theory on Rates for Electron Transfer Mediated by a Midway Molecule, Bridging between Superexchange and Sequential Processes

A typical example of electron transfer (ET) mediated by a midway molecule M is the initial ultrafast ET from the special pair to bacteriopheophytin in the reaction center of bacterial photosynthesis, where the donor D and the acceptor A are so far apart (∼17 Å) that ET is mediated by a bacteriochlor...

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Veröffentlicht in:The journal of physical chemistry. B 2001-10, Vol.105 (39), p.9603-9622
Hauptverfasser: Sumi, Hitoshi, Kakitani, Toshiaki
Format: Artikel
Sprache:eng
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