A Continuous Wave and Pulse EPR and ENDOR Investigation of Oxygenated Co(II) Corrin Complexes

Heptamethyl cobyrinate perchlorate, [Cob(II)ester]ClO4, has the relevant structural features of base-off B12r, the reduced Co(II) form of vitamin B12. The reversible oxygenation behavior of this complex in different solvents is investigated using continuous wave (cw) EPR at X-band and compared with...

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Veröffentlicht in:	The journal of physical chemistry. B 2001-08, Vol.105 (31), p.7554-7563
Hauptverfasser:	Van Doorslaer, Sabine, Schweiger, Arthur, Kräutler, Bernhard
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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