Mechanism and Stereochemistry of the Water-Exchange Reaction on Aqua Pentaammine and Aqua Pentakis-Methylamine Rhodium(III) Ions

The water-exchange reaction on Rh(NH3)5OH2 3+ and Rh(NH2CH3)5OH2 3+ has been investigated by ab initio calculations on all stationary points of the potential energy surface (reactants/products, transition states, and intermediates, if there are any). The water-exchange on Rh(NH3)5OH2 3+ proceeds via...

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Veröffentlicht in:	The journal of physical chemistry. A, Molecules, spectroscopy, kinetics, environment, & general theory Molecules, spectroscopy, kinetics, environment, & general theory, 2000-07, Vol.104 (27), p.6439-6446
1. Verfasser:	Rotzinger, François P
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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