A Determination of the Bond Dissociation Energy (D 0(H−SH)):  Threshold Ion-Pair Production Spectroscopy (TIPPS) of a Triatomic Molecule

We present the first threshold ion-pair production spectrum of a triatomic molecule. We have recorded the ion-pair yield spectrum and TIPP spectrum for the H2S → H++SH- ion-pair channel using single-photon excitation. From the TIPP spectrum, we have determined the H−SH bond energy (31451 ± 4 cm-1) t...

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Veröffentlicht in:	The journal of physical chemistry. A, Molecules, spectroscopy, kinetics, environment, & general theory Molecules, spectroscopy, kinetics, environment, & general theory, 2000-05, Vol.104 (19), p.4339-4342
Hauptverfasser:	Shiell, R. C, Hu, X. K, Hu, Q. J, Hepburn, J. W
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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