Intramolecular Cyclization of Radicals Generated from α-Halomethylsulfonamides

A series of homologous α-sulfonamidyl radicals has been generated by reaction of α-halomethyl precursors with tri-n-butyltin hydride under AIBN catalysis. The intramolecular cyclization capability of these highly reactive intermediates has been evaluated. Where possible, five-membered sultams are fo...

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Veröffentlicht in:Journal of organic chemistry 1999-12, Vol.64 (25), p.9225-9229
Hauptverfasser: Leit, Silvana M, Paquette, Leo A
Format: Artikel
Sprache:eng
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