Catalysis of Anilide Ethanolysis by Barium− and Strontium−Ethoxide Pairs and Their Complexes with 18-Crown-6

The metal-bound ethoxide species that are quantitatively formed upon mixing equimolar amounts of Me4NOEt and alkaline-earth (Ba, Sr) metal salt in ethanol solution are more reactive than free ethoxide in the cleavage of simple activated amides (e.g. N-methyl-2,2,2-trifluoroacetanilide) lacking any d...

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Veröffentlicht in:	Journal of organic chemistry 1998-09, Vol.63 (19), p.6476-6479
Hauptverfasser:	Cacciapaglia, Roberta, Stefano, Kelderman, Erik, Mandolini, Luigi, Spadola, Francesco
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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