Characterization of Acyl Adenyl Anhydrides:  Differences in the Hydrolytic Rates of Fatty Acyl-AMP and Aminoacyl-AMP Derivatives

An improved procedure has been developed to prepare RCOOPO2-Ado (R = C6H13 and C15H31), the intermediate in the enzymatic synthesis of acyl-CoA's. The product has been characterized by spectral methods which, in turn, were used to define the hydrolysis rates of RCO-AMP. When R is a fatty acyl g...

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Veröffentlicht in:	Journal of organic chemistry 1998-11, Vol.63 (24), p.8661-8667
Hauptverfasser:	Schall, Otto F, Suzuki, Iwao, Murray, Clare L, Gordon, Jeffrey I, Gokel, George W
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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