New Versatile Fluorinated Chiral Building Blocks:  Synthesis and Reactivity of Optically Pure α-(Fluoroalkyl)-β-sulfinylenamines

Efficient synthesis of optically pure α-(fluoroalkyl)-β-sulfinyl enamines has been achieved by aza-Wittig reaction of triphenyliminophosphoranes with the corresponding α-fluorinated-α‘-sulfinyl ketones. The title compounds 3,4 showed an overwhelming preference for the Z stereochemistry of the enamin...

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Veröffentlicht in:	Journal of organic chemistry 1996-05, Vol.61 (10), p.3375-3387
Hauptverfasser:	Arnone, Alberto, Bravo, Pierfrancesco, Capelli, Silvia, Fronza, Giovanni, Meille, Stefano V, Zanda, Matteo, Cavicchio, Giancarlo, Crucianelli, Marcello
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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