Reactions of a Silanediyl with Carbon−Oxygen and Carbon−Nitrogen Double Bonds

Silanediyl 2 (generated by thermolysis of cyclotrisilane 1) reacts with benzophenone, tetracyclone, and fluorenone to yield products, which may originate from highly reactive siloxiranes as intermediates. However, using adamantanone as ketone, stable siloxirane 24 is obtained. The interaction of 2 w...

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Veröffentlicht in:	Journal of organic chemistry 1996-05, Vol.61 (10), p.3315-3319
Hauptverfasser:	Belzner, Johannes, Ihmels, Heiko, Pauletto, Lara, Noltemeyer, Matthias
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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