Mn-Mediated Coupling of Alkyl Iodides and Chiral N-Acylhydrazones:  Optimization, Scope, and Evidence for a Radical Mechanism

Stereoselective radical additions have excellent potential as mild, nonbasic carbon−carbon bond constructions for direct asymmetric amine synthesis. Efficient intermolecular radical addition to CN bonds with acyclic stereocontrol has previously been limited mainly to secondary and tertiary radicals...

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Veröffentlicht in:	Journal of organic chemistry 2006-09, Vol.71 (18), p.7016-7027
Hauptverfasser:	Friestad, Gregory K, Marié, Jean-Charles, Suh, Qin, Jun
Format:	Artikel
Sprache:	eng
Schlagworte:	Chemistry Exact sciences and technology Free Radicals Heterocyclic compounds Heterocyclic compounds with n hetero atom and also o and/or s, se, te hetero atoms Hydrazones - chemistry Iodides - chemistry Kinetics and mechanisms Manganese - chemistry Mechanics Organic chemistry Photochemistry - methods Preparations and properties Reactivity and mechanisms Stereoisomerism
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