Synthesis of Enantiopure Sulfinimines (Thiooxime S-Oxides) Catalyzed by Yb(OTf)3 from p-Toluenesulfinamide and Aldehydes in Mild Reaction Conditions

Enantiomerically pure sulfinimines as important building blocks in the asymmetric synthesis of amine derivatives are prepared in good to excellent yields from chiral p-toluenesulfinamide with aromatic, heteroaromatic, and aliphatic aldehydes. The unprecedented feature of the reported procedure is th...

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Veröffentlicht in:Journal of organic chemistry 2005-02, Vol.70 (3), p.1081-1083
Hauptverfasser: Jiang, Zhi-Yong, Chan, W. H, Lee, A. W. M
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Sprache:eng
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