A Study of C−F···M+ Interaction:  Alkali Metal Complexes of the Fluorine-Containing Cage Compound

The C−F···M+ interaction was investigated by employing a cage compound 1 that has four fluorobenzene units. The NMR (1H, 13C, and 19F) spectra and X-ray crystallographic analyses of 1 and its metal complexes showed clear evidence of the interaction. Short C−F···M+ distances (C−F···K+, 2.755 and 2.72...

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Veröffentlicht in:Journal of organic chemistry 2001-04, Vol.66 (8), p.2778-2783
Hauptverfasser: Takemura, Hiroyuki, Kon, Noriyoshi, Kotoku, Masayuki, Nakashima, Sachiko, Otsuka, Kazuhiro, Yasutake, Mikio, Shinmyozu, Teruo, Inazu, Takahiko
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Sprache:eng
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