Formic acid and the high-temperature reductive desulfurization of aromatic sulfides

When diphenyl sulfide is heated with formic acid to 450/sup 0/C, it is converted to benzene, toluene, thiophenol, thioanisole, and benzoic acid. By increasing the time of reaction, diphenyl sulfide is converted completely to benzene and toluene. The mechanism of toluene and benzoic acid formation is...

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Veröffentlicht in:	J. Org. Chem.; (United States) 1982-10, Vol.47 (21), p.4107-4110
Hauptverfasser:	Van Buren, Rick L, Baltisberger, Richard J, Woolsey, Neil F, Stenberg, Virgil I
Format:	Artikel
Sprache:	eng
Schlagworte:	01 COAL, LIGNITE, AND PEAT 010402 - Coal, Lignite, & Peat- Purification & Upgrading 400301 - Organic Chemistry- Chemical & Physicochemical Properties- (-1987) AROMATICS CARBOXYLIC ACIDS CHEMICAL REACTION KINETICS CHEMICAL REACTIONS CONVERSION DESULFURIZATION FORMIC ACID HIGH TEMPERATURE INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY KINETICS MONOCARBOXYLIC ACIDS ORGANIC ACIDS ORGANIC COMPOUNDS ORGANIC SULFUR COMPOUNDS REACTION KINETICS TEMPERATURE EFFECTS
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