Polymeric Microcapsules of Alachlor and Metolachlor: Preparation and Evaluation of Controlled-Release Properties
The microencapsulation of alachlor and metolachlor in the polymers cellulose acetate butyrate, ethyl cellulose, poly(methyl methacrylate), and poly(α-methylstyrene) with different emulsifiers is described. The controlled-release properties of these formulations were measured under greenhouse conditi...
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Veröffentlicht in: | Journal of agricultural and food chemistry 1999-07, Vol.47 (7), p.2908-2913 |
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creator | Dowler, Clyde C Dailey, Oliver D Mullinix, Ben G |
description | The microencapsulation of alachlor and metolachlor in the polymers cellulose acetate butyrate, ethyl cellulose, poly(methyl methacrylate), and poly(α-methylstyrene) with different emulsifiers is described. The controlled-release properties of these formulations were measured under greenhouse conditions on barnyardgrass, crowfootgrass, smallflower morningglory, and Palmer amaranth. The emulsifiers had little effect on the activity of the herbicides. The herbicidal activities of the poly(methyl methacrylate) and poly(α-methylstyrene) formulations were consistently lower on all weed species when compared to the activities of the cellulose acetate butyrate, ethyl cellulose, and commercial formulations. The ethyl cellulose formulation of alachlor exhibited controlled-release properties. The results with metolachlor were similar to those with alachlor except that none of the metolachlor formulations exhibited efficacy superior to that of the commercial formulation or controlled release properties. Keywords: Formulation; microencapsulation; persistence; herbicide activity |
doi_str_mv | 10.1021/jf981269t |
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The controlled-release properties of these formulations were measured under greenhouse conditions on barnyardgrass, crowfootgrass, smallflower morningglory, and Palmer amaranth. The emulsifiers had little effect on the activity of the herbicides. The herbicidal activities of the poly(methyl methacrylate) and poly(α-methylstyrene) formulations were consistently lower on all weed species when compared to the activities of the cellulose acetate butyrate, ethyl cellulose, and commercial formulations. The ethyl cellulose formulation of alachlor exhibited controlled-release properties. The results with metolachlor were similar to those with alachlor except that none of the metolachlor formulations exhibited efficacy superior to that of the commercial formulation or controlled release properties. Keywords: Formulation; microencapsulation; persistence; herbicide activity</description><identifier>ISSN: 0021-8561</identifier><identifier>EISSN: 1520-5118</identifier><identifier>DOI: 10.1021/jf981269t</identifier><identifier>PMID: 10552585</identifier><identifier>CODEN: JAFCAU</identifier><language>eng</language><publisher>Washington, DC: American Chemical Society</publisher><subject>Acetamides - administration & dosage ; Acetamides - chemistry ; Agronomy. Soil science and plant productions ; alachlor ; Biological and medical sciences ; Capsules ; Chemical control ; controlled release ; emulsifiers ; Evaluation Studies as Topic ; formulations ; Fundamental and applied biological sciences. Psychology ; herbicidal activity ; herbicidal properties ; Herbicides - administration & dosage ; Herbicides - chemistry ; metolachlor ; microencapsulation ; Parasitic plants. Weeds ; Phytopathology. Animal pests. Plant and forest protection ; Polymers ; Soil and water pollution ; Soil science ; Weeds</subject><ispartof>Journal of agricultural and food chemistry, 1999-07, Vol.47 (7), p.2908-2913</ispartof><rights>Copyright © 1999 American Chemical Society</rights><rights>2000 INIST-CNRS</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-a468t-1fa8e06d8764626cc8db20a4f4525be6682fbb42d1315d0220279e068faff0c03</citedby><cites>FETCH-LOGICAL-a468t-1fa8e06d8764626cc8db20a4f4525be6682fbb42d1315d0220279e068faff0c03</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://pubs.acs.org/doi/pdf/10.1021/jf981269t$$EPDF$$P50$$Gacs$$H</linktopdf><linktohtml>$$Uhttps://pubs.acs.org/doi/10.1021/jf981269t$$EHTML$$P50$$Gacs$$H</linktohtml><link.rule.ids>314,776,780,2752,27053,27901,27902,56713,56763</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=1217276$$DView record in Pascal Francis$$Hfree_for_read</backlink><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/10552585$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Dowler, Clyde C</creatorcontrib><creatorcontrib>Dailey, Oliver D</creatorcontrib><creatorcontrib>Mullinix, Ben G</creatorcontrib><title>Polymeric Microcapsules of Alachlor and Metolachlor: Preparation and Evaluation of Controlled-Release Properties</title><title>Journal of agricultural and food chemistry</title><addtitle>J. Agric. Food Chem</addtitle><description>The microencapsulation of alachlor and metolachlor in the polymers cellulose acetate butyrate, ethyl cellulose, poly(methyl methacrylate), and poly(α-methylstyrene) with different emulsifiers is described. The controlled-release properties of these formulations were measured under greenhouse conditions on barnyardgrass, crowfootgrass, smallflower morningglory, and Palmer amaranth. The emulsifiers had little effect on the activity of the herbicides. The herbicidal activities of the poly(methyl methacrylate) and poly(α-methylstyrene) formulations were consistently lower on all weed species when compared to the activities of the cellulose acetate butyrate, ethyl cellulose, and commercial formulations. The ethyl cellulose formulation of alachlor exhibited controlled-release properties. The results with metolachlor were similar to those with alachlor except that none of the metolachlor formulations exhibited efficacy superior to that of the commercial formulation or controlled release properties. Keywords: Formulation; microencapsulation; persistence; herbicide activity</description><subject>Acetamides - administration & dosage</subject><subject>Acetamides - chemistry</subject><subject>Agronomy. Soil science and plant productions</subject><subject>alachlor</subject><subject>Biological and medical sciences</subject><subject>Capsules</subject><subject>Chemical control</subject><subject>controlled release</subject><subject>emulsifiers</subject><subject>Evaluation Studies as Topic</subject><subject>formulations</subject><subject>Fundamental and applied biological sciences. Psychology</subject><subject>herbicidal activity</subject><subject>herbicidal properties</subject><subject>Herbicides - administration & dosage</subject><subject>Herbicides - chemistry</subject><subject>metolachlor</subject><subject>microencapsulation</subject><subject>Parasitic plants. Weeds</subject><subject>Phytopathology. Animal pests. Plant and forest protection</subject><subject>Polymers</subject><subject>Soil and water pollution</subject><subject>Soil science</subject><subject>Weeds</subject><issn>0021-8561</issn><issn>1520-5118</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>1999</creationdate><recordtype>article</recordtype><sourceid>EIF</sourceid><recordid>eNptkM1u1DAUhS1ERYfCgheALGDBIuXaiX_CrhqVUqkVI_ojdtaNY0MGTxzZGUR3bPuaPAluMyosWF1dne9c3XMIeUHhkAKj79auUZSJZnpEFpQzKDml6jFZQBZLxQXdJ09TWgOA4hKekH0KnDOu-IKkVfA3Gxt7U5z3JgaDY9p6m4rgiiOP5psPscChK87tFHb7-9-_botVtCNGnPow3OvHP9Bv5zVbl2GYYvDeduVn6y0mmw1htHHqbXpG9hz6ZJ_v5gG5-nB8ufxYnn06OV0enZVYCzWV1KGyIDolRS2YMEZ1LQOsXZ1_b60Qirm2rVlHK8o7YAyYbLJBOXQODFQH5O18N-dKKVqnx9hvMN5oCvquOP1QXGZfzuy4bTe2-4ecm8rA6x2AyaB3EQfTp78co5JJkbFyxvo02Z8PMsbvWshKcn25utAMrr9U_Br03Y-vZt5h0Pg15pNXFwxoBayppBRNJt7MBJqk12Ebh9zZfxL8AUGdm8s</recordid><startdate>19990701</startdate><enddate>19990701</enddate><creator>Dowler, Clyde C</creator><creator>Dailey, Oliver D</creator><creator>Mullinix, Ben G</creator><general>American Chemical Society</general><scope>FBQ</scope><scope>BSCLL</scope><scope>IQODW</scope><scope>CGR</scope><scope>CUY</scope><scope>CVF</scope><scope>ECM</scope><scope>EIF</scope><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>19990701</creationdate><title>Polymeric Microcapsules of Alachlor and Metolachlor: Preparation and Evaluation of Controlled-Release Properties</title><author>Dowler, Clyde C ; Dailey, Oliver D ; Mullinix, Ben G</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-a468t-1fa8e06d8764626cc8db20a4f4525be6682fbb42d1315d0220279e068faff0c03</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>1999</creationdate><topic>Acetamides - administration & dosage</topic><topic>Acetamides - chemistry</topic><topic>Agronomy. Soil science and plant productions</topic><topic>alachlor</topic><topic>Biological and medical sciences</topic><topic>Capsules</topic><topic>Chemical control</topic><topic>controlled release</topic><topic>emulsifiers</topic><topic>Evaluation Studies as Topic</topic><topic>formulations</topic><topic>Fundamental and applied biological sciences. Psychology</topic><topic>herbicidal activity</topic><topic>herbicidal properties</topic><topic>Herbicides - administration & dosage</topic><topic>Herbicides - chemistry</topic><topic>metolachlor</topic><topic>microencapsulation</topic><topic>Parasitic plants. Weeds</topic><topic>Phytopathology. Animal pests. Plant and forest protection</topic><topic>Polymers</topic><topic>Soil and water pollution</topic><topic>Soil science</topic><topic>Weeds</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Dowler, Clyde C</creatorcontrib><creatorcontrib>Dailey, Oliver D</creatorcontrib><creatorcontrib>Mullinix, Ben G</creatorcontrib><collection>AGRIS</collection><collection>Istex</collection><collection>Pascal-Francis</collection><collection>Medline</collection><collection>MEDLINE</collection><collection>MEDLINE (Ovid)</collection><collection>MEDLINE</collection><collection>MEDLINE</collection><collection>PubMed</collection><collection>CrossRef</collection><jtitle>Journal of agricultural and food chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Dowler, Clyde C</au><au>Dailey, Oliver D</au><au>Mullinix, Ben G</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Polymeric Microcapsules of Alachlor and Metolachlor: Preparation and Evaluation of Controlled-Release Properties</atitle><jtitle>Journal of agricultural and food chemistry</jtitle><addtitle>J. Agric. Food Chem</addtitle><date>1999-07-01</date><risdate>1999</risdate><volume>47</volume><issue>7</issue><spage>2908</spage><epage>2913</epage><pages>2908-2913</pages><issn>0021-8561</issn><eissn>1520-5118</eissn><coden>JAFCAU</coden><abstract>The microencapsulation of alachlor and metolachlor in the polymers cellulose acetate butyrate, ethyl cellulose, poly(methyl methacrylate), and poly(α-methylstyrene) with different emulsifiers is described. The controlled-release properties of these formulations were measured under greenhouse conditions on barnyardgrass, crowfootgrass, smallflower morningglory, and Palmer amaranth. The emulsifiers had little effect on the activity of the herbicides. The herbicidal activities of the poly(methyl methacrylate) and poly(α-methylstyrene) formulations were consistently lower on all weed species when compared to the activities of the cellulose acetate butyrate, ethyl cellulose, and commercial formulations. The ethyl cellulose formulation of alachlor exhibited controlled-release properties. The results with metolachlor were similar to those with alachlor except that none of the metolachlor formulations exhibited efficacy superior to that of the commercial formulation or controlled release properties. Keywords: Formulation; microencapsulation; persistence; herbicide activity</abstract><cop>Washington, DC</cop><pub>American Chemical Society</pub><pmid>10552585</pmid><doi>10.1021/jf981269t</doi><tpages>6</tpages></addata></record> |
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subjects | Acetamides - administration & dosage Acetamides - chemistry Agronomy. Soil science and plant productions alachlor Biological and medical sciences Capsules Chemical control controlled release emulsifiers Evaluation Studies as Topic formulations Fundamental and applied biological sciences. Psychology herbicidal activity herbicidal properties Herbicides - administration & dosage Herbicides - chemistry metolachlor microencapsulation Parasitic plants. Weeds Phytopathology. Animal pests. Plant and forest protection Polymers Soil and water pollution Soil science Weeds |
title | Polymeric Microcapsules of Alachlor and Metolachlor: Preparation and Evaluation of Controlled-Release Properties |
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