Solubility of Anthracene in Multicomponent Solvent Mixtures Containing Propanol, Butanol, and Alkanes

Experimental solubilities are reported for anthracene dissolved in ternary solvent mixtures 1-propanol + 2-propanol + cyclohexane and 1-butanol + 2-butanol + cyclohexane, for anthracene dissolved in the heptanary solvent mixture 1-propanol + 2-propanol + 1-butanol + 2-butanol + cyclohexane + heptane...

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Veröffentlicht in:Journal of chemical and engineering data 1999-07, Vol.44 (4), p.798-802
Hauptverfasser: Deng, Taihe, Horiuchi, Satoru, De Fina, Karina M, Hernández, Carmen E, Acree, William E
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container_end_page 802
container_issue 4
container_start_page 798
container_title Journal of chemical and engineering data
container_volume 44
creator Deng, Taihe
Horiuchi, Satoru
De Fina, Karina M
Hernández, Carmen E
Acree, William E
description Experimental solubilities are reported for anthracene dissolved in ternary solvent mixtures 1-propanol + 2-propanol + cyclohexane and 1-butanol + 2-butanol + cyclohexane, for anthracene dissolved in the heptanary solvent mixture 1-propanol + 2-propanol + 1-butanol + 2-butanol + cyclohexane + heptane + 2,2,4-trimethylpentane, and for anthracene dissolved in binary solvent heptane + 2,2,4-trimethylpentane at 298.15 K. For the two ternary solvent systems anthracene mole fraction solubilities are reported at 19 different ternary compositions spanning the entire mole fraction range. In the case of heptanary solvent system, solubility data was measured at eight solvent compositions. Results of these measurements are used to test the predictive ability of the combined nearly ideal multiple solvent (NIMS)/Redlich−Kister and combined NIMS/BAB equations. Computations showed that both solution models provided reasonably accurate predictions for how the mole fraction solubility varied with solvent compositions. Deviations between predicted and experimental values were on the order of ±0.95% for the better of the two predictive equations.
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Results of these measurements are used to test the predictive ability of the combined nearly ideal multiple solvent (NIMS)/Redlich−Kister and combined NIMS/BAB equations. Computations showed that both solution models provided reasonably accurate predictions for how the mole fraction solubility varied with solvent compositions. Deviations between predicted and experimental values were on the order of ±0.95% for the better of the two predictive equations.</abstract><cop>Washington, DC</cop><pub>American Chemical Society</pub><doi>10.1021/je9900070</doi><tpages>5</tpages><oa>free_for_read</oa></addata></record>
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Exact sciences and technology
General and physical chemistry
Solubility
Solutions
title Solubility of Anthracene in Multicomponent Solvent Mixtures Containing Propanol, Butanol, and Alkanes
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