Thermodynamic Properties of the Ternary Mixture Acetone + Methanol + Ethanol at 298.15 K

Speeds of sound, densities, and refractive indices of the ternary mixture acetone + methanol + ethanol have been measured at 298.15 K and atmospheric pressure. The excess molar volumes, changes of refractive indices, and isentropic compressibilities were determined from the experimental data. Severa...

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Veröffentlicht in:Journal of chemical and engineering data 1998-09, Vol.43 (5), p.776-780
Hauptverfasser: Iglesias, Miguel, Orge, Beatriz, Piñeiro, Manuel M, de Cominges, Beatriz E, Marino, Gonzalo, Tojo, Jose
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container_end_page 780
container_issue 5
container_start_page 776
container_title Journal of chemical and engineering data
container_volume 43
creator Iglesias, Miguel
Orge, Beatriz
Piñeiro, Manuel M
de Cominges, Beatriz E
Marino, Gonzalo
Tojo, Jose
description Speeds of sound, densities, and refractive indices of the ternary mixture acetone + methanol + ethanol have been measured at 298.15 K and atmospheric pressure. The excess molar volumes, changes of refractive indices, and isentropic compressibilities were determined from the experimental data. Several methods for predicting multicomponent derived properties from binary data were tested. The Peng−Robinson and Soave−Redlich−Kwong equations of state were also applied, with three different mixing rules, to calculate binary interaction parameters and predict ternary excess volumes, satisfactory results being obtained for this mixture.
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subjects Chemical thermodynamics
Chemistry
Exact sciences and technology
General and physical chemistry
Mixtures
Thermodynamic properties
title Thermodynamic Properties of the Ternary Mixture Acetone + Methanol + Ethanol at 298.15 K
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