Thermodynamic Properties of the Ternary Mixture Acetone + Methanol + Ethanol at 298.15 K
Speeds of sound, densities, and refractive indices of the ternary mixture acetone + methanol + ethanol have been measured at 298.15 K and atmospheric pressure. The excess molar volumes, changes of refractive indices, and isentropic compressibilities were determined from the experimental data. Severa...
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Veröffentlicht in: | Journal of chemical and engineering data 1998-09, Vol.43 (5), p.776-780 |
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container_title | Journal of chemical and engineering data |
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creator | Iglesias, Miguel Orge, Beatriz Piñeiro, Manuel M de Cominges, Beatriz E Marino, Gonzalo Tojo, Jose |
description | Speeds of sound, densities, and refractive indices of the ternary mixture acetone + methanol + ethanol have been measured at 298.15 K and atmospheric pressure. The excess molar volumes, changes of refractive indices, and isentropic compressibilities were determined from the experimental data. Several methods for predicting multicomponent derived properties from binary data were tested. The Peng−Robinson and Soave−Redlich−Kwong equations of state were also applied, with three different mixing rules, to calculate binary interaction parameters and predict ternary excess volumes, satisfactory results being obtained for this mixture. |
doi_str_mv | 10.1021/je980041z |
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The excess molar volumes, changes of refractive indices, and isentropic compressibilities were determined from the experimental data. Several methods for predicting multicomponent derived properties from binary data were tested. The Peng−Robinson and Soave−Redlich−Kwong equations of state were also applied, with three different mixing rules, to calculate binary interaction parameters and predict ternary excess volumes, satisfactory results being obtained for this mixture.</description><identifier>ISSN: 0021-9568</identifier><identifier>EISSN: 1520-5134</identifier><identifier>DOI: 10.1021/je980041z</identifier><identifier>CODEN: JCEAAX</identifier><language>eng</language><publisher>Washington, DC: American Chemical Society</publisher><subject>Chemical thermodynamics ; Chemistry ; Exact sciences and technology ; General and physical chemistry ; Mixtures ; Thermodynamic properties</subject><ispartof>Journal of chemical and engineering data, 1998-09, Vol.43 (5), p.776-780</ispartof><rights>Copyright © 1998 American Chemical Society</rights><rights>1998 INIST-CNRS</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-a342t-2ed77c908a2014c76eb1582c916c08a6d218bc1888b1feca6a5e479074a4d2023</citedby><cites>FETCH-LOGICAL-a342t-2ed77c908a2014c76eb1582c916c08a6d218bc1888b1feca6a5e479074a4d2023</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://pubs.acs.org/doi/pdf/10.1021/je980041z$$EPDF$$P50$$Gacs$$H</linktopdf><linktohtml>$$Uhttps://pubs.acs.org/doi/10.1021/je980041z$$EHTML$$P50$$Gacs$$H</linktohtml><link.rule.ids>314,776,780,2752,27053,27901,27902,56713,56763</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=2398845$$DView record in Pascal Francis$$Hfree_for_read</backlink></links><search><creatorcontrib>Iglesias, Miguel</creatorcontrib><creatorcontrib>Orge, Beatriz</creatorcontrib><creatorcontrib>Piñeiro, Manuel M</creatorcontrib><creatorcontrib>de Cominges, Beatriz E</creatorcontrib><creatorcontrib>Marino, Gonzalo</creatorcontrib><creatorcontrib>Tojo, Jose</creatorcontrib><title>Thermodynamic Properties of the Ternary Mixture Acetone + Methanol + Ethanol at 298.15 K</title><title>Journal of chemical and engineering data</title><addtitle>J. Chem. Eng. Data</addtitle><description>Speeds of sound, densities, and refractive indices of the ternary mixture acetone + methanol + ethanol have been measured at 298.15 K and atmospheric pressure. The excess molar volumes, changes of refractive indices, and isentropic compressibilities were determined from the experimental data. Several methods for predicting multicomponent derived properties from binary data were tested. The Peng−Robinson and Soave−Redlich−Kwong equations of state were also applied, with three different mixing rules, to calculate binary interaction parameters and predict ternary excess volumes, satisfactory results being obtained for this mixture.</description><subject>Chemical thermodynamics</subject><subject>Chemistry</subject><subject>Exact sciences and technology</subject><subject>General and physical chemistry</subject><subject>Mixtures</subject><subject>Thermodynamic properties</subject><issn>0021-9568</issn><issn>1520-5134</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>1998</creationdate><recordtype>article</recordtype><recordid>eNptkF9LwzAUxYMoOKcPfoM86INIZ5I2TfI4xqayDYdW8C1k6S3r7NqRdLD56Y107Mmne7jnd_9wELqlZEAJo09rUJKQhP6coR7ljEScxsk56pFgRoqn8hJdeb8mgRGM9tBXtgK3afJDbTalxQvXbMG1JXjcFLhdAc7A1cYd8LzctzsHeGihbWrAj3gO7crUTRXk-KhMi5mSA8rx9BpdFKbycHOsffQ5GWejl2j29vw6Gs4iEyesjRjkQlhFpGGEJlaksKRcMqtoakMzzRmVS0ullEtagDWp4ZAIRURikpwRFvfRQ7fXusZ7B4XeunITPtaU6L9I9CmSwN517NZ4a6rCmdqW_jTAYiVlwgMWdVjpW9ifbOO-dSpiwXW2-NCxep9wxqdaBP6-4431et3sQmCV_-f8L6xpeTo</recordid><startdate>19980910</startdate><enddate>19980910</enddate><creator>Iglesias, Miguel</creator><creator>Orge, Beatriz</creator><creator>Piñeiro, Manuel M</creator><creator>de Cominges, Beatriz E</creator><creator>Marino, Gonzalo</creator><creator>Tojo, Jose</creator><general>American Chemical Society</general><scope>BSCLL</scope><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>19980910</creationdate><title>Thermodynamic Properties of the Ternary Mixture Acetone + Methanol + Ethanol at 298.15 K</title><author>Iglesias, Miguel ; Orge, Beatriz ; Piñeiro, Manuel M ; de Cominges, Beatriz E ; Marino, Gonzalo ; Tojo, Jose</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-a342t-2ed77c908a2014c76eb1582c916c08a6d218bc1888b1feca6a5e479074a4d2023</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>1998</creationdate><topic>Chemical thermodynamics</topic><topic>Chemistry</topic><topic>Exact sciences and technology</topic><topic>General and physical chemistry</topic><topic>Mixtures</topic><topic>Thermodynamic properties</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Iglesias, Miguel</creatorcontrib><creatorcontrib>Orge, Beatriz</creatorcontrib><creatorcontrib>Piñeiro, Manuel M</creatorcontrib><creatorcontrib>de Cominges, Beatriz E</creatorcontrib><creatorcontrib>Marino, Gonzalo</creatorcontrib><creatorcontrib>Tojo, Jose</creatorcontrib><collection>Istex</collection><collection>Pascal-Francis</collection><collection>CrossRef</collection><jtitle>Journal of chemical and engineering data</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Iglesias, Miguel</au><au>Orge, Beatriz</au><au>Piñeiro, Manuel M</au><au>de Cominges, Beatriz E</au><au>Marino, Gonzalo</au><au>Tojo, Jose</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Thermodynamic Properties of the Ternary Mixture Acetone + Methanol + Ethanol at 298.15 K</atitle><jtitle>Journal of chemical and engineering data</jtitle><addtitle>J. Chem. Eng. Data</addtitle><date>1998-09-10</date><risdate>1998</risdate><volume>43</volume><issue>5</issue><spage>776</spage><epage>780</epage><pages>776-780</pages><issn>0021-9568</issn><eissn>1520-5134</eissn><coden>JCEAAX</coden><abstract>Speeds of sound, densities, and refractive indices of the ternary mixture acetone + methanol + ethanol have been measured at 298.15 K and atmospheric pressure. The excess molar volumes, changes of refractive indices, and isentropic compressibilities were determined from the experimental data. Several methods for predicting multicomponent derived properties from binary data were tested. The Peng−Robinson and Soave−Redlich−Kwong equations of state were also applied, with three different mixing rules, to calculate binary interaction parameters and predict ternary excess volumes, satisfactory results being obtained for this mixture.</abstract><cop>Washington, DC</cop><pub>American Chemical Society</pub><doi>10.1021/je980041z</doi><tpages>5</tpages></addata></record> |
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subjects | Chemical thermodynamics Chemistry Exact sciences and technology General and physical chemistry Mixtures Thermodynamic properties |
title | Thermodynamic Properties of the Ternary Mixture Acetone + Methanol + Ethanol at 298.15 K |
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