Isothermal Vapor−Liquid Equilibria Measurements, Excess Molar Enthalpies, and Excess Molar Volumes of Dimethyl Carbonate + Methanol, + Ethanol, and + Propan-1-ol at 313.15 K

Isothermal vapor−liquid equilibria (VLE), excess molar enthalpies, , and excess molar volumes, , have been measured for the binary mixtures dimethyl carbonate + methanol, + ethanol, or + propan-1-ol at 313.15 K and at atmospheric pressure. The three mixtures exhibit large deviations from ideality, s...

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Veröffentlicht in:	Journal of chemical and engineering data 1997-07, Vol.42 (4), p.705-709
Hauptverfasser:	Comelli, Fabio, Francesconi, Romolo
Format:	Artikel
Sprache:	eng
Schlagworte:	Chemistry Exact sciences and technology General and physical chemistry Liquid-vapor equilibria Phase equilibria
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container_title	Journal of chemical and engineering data
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creator	Comelli, Fabio Francesconi, Romolo
description	Isothermal vapor−liquid equilibria (VLE), excess molar enthalpies, , and excess molar volumes, , have been measured for the binary mixtures dimethyl carbonate + methanol, + ethanol, or + propan-1-ol at 313.15 K and at atmospheric pressure. The three mixtures exhibit large deviations from ideality, showing an azeotrope at 0.14, 0.42, and 0.78 mole fraction of dimethyl carbonate, respectively. The VLE data were correlated by the Wilson equation and the appropriate parameters are reported. and values have been correlated using the Redlich−Kister equation by the method of least-squares.
doi_str_mv	10.1021/je960321j
format	Article
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The three mixtures exhibit large deviations from ideality, showing an azeotrope at 0.14, 0.42, and 0.78 mole fraction of dimethyl carbonate, respectively. 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Chem. Eng. Data</addtitle><description>Isothermal vapor−liquid equilibria (VLE), excess molar enthalpies, , and excess molar volumes, , have been measured for the binary mixtures dimethyl carbonate + methanol, + ethanol, or + propan-1-ol at 313.15 K and at atmospheric pressure. The three mixtures exhibit large deviations from ideality, showing an azeotrope at 0.14, 0.42, and 0.78 mole fraction of dimethyl carbonate, respectively. The VLE data were correlated by the Wilson equation and the appropriate parameters are reported. and values have been correlated using the Redlich−Kister equation by the method of least-squares.</description><subject>Chemistry</subject><subject>Exact sciences and technology</subject><subject>General and physical chemistry</subject><subject>Liquid-vapor equilibria</subject><subject>Phase equilibria</subject><issn>0021-9568</issn><issn>1520-5134</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>1997</creationdate><recordtype>article</recordtype><recordid>eNptkM9u1DAQxi0EEkvLgTfwAQ6oTes_cRwf0ZJC1V1RqWUPXKxx1tZmceLUzkrtG3DmRXgnngRXCytV4jIz0vebb_QNQm8oOaOE0fOtVRXhjG6foRkVjBSC8vI5mpEsFkpU9Uv0KqUtIaSUjM7Qr8sUpo2NPXi8gjHE3z9-Lrq7XbfGTa6-M7EDvLSQdtH2dpjSKW7uW5sSXgYPETfDtAE_djYLMKyfiqvgd71NODj8sevttHnweA7RhAEmi0-yb14egj_Nc_NvfHQ5wdcxjDAUtAgew4Q55WdU4Ktj9MKBT_b1336Evl40t_PPxeLLp8v5h0UBjKupUFRR54xqc3pnDK_bkpaVEYIJUzEuwTlljWFtzVglJVGCMWMtXSuhlDM1P0Lv975tDClF6_QYux7ig6ZEP35aHz6d2bd7doTUgncRhrZLhwUmK8FqmbFij3VpsvcHGeJ3XUkuhb69vtGr5cU3Wd4sNM38uz0PbdLbsItDDvyf838AYNWZGQ</recordid><startdate>19970714</startdate><enddate>19970714</enddate><creator>Comelli, Fabio</creator><creator>Francesconi, Romolo</creator><general>American Chemical Society</general><scope>BSCLL</scope><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>19970714</creationdate><title>Isothermal Vapor−Liquid Equilibria Measurements, Excess Molar Enthalpies, and Excess Molar Volumes of Dimethyl Carbonate + Methanol, + Ethanol, and + Propan-1-ol at 313.15 K</title><author>Comelli, Fabio ; Francesconi, Romolo</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-a239t-9191ffb9c134fbb38c4146b5525b6237aff9ebb2c82267709522bee1d9599fb83</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>1997</creationdate><topic>Chemistry</topic><topic>Exact sciences and technology</topic><topic>General and physical chemistry</topic><topic>Liquid-vapor equilibria</topic><topic>Phase equilibria</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Comelli, Fabio</creatorcontrib><creatorcontrib>Francesconi, Romolo</creatorcontrib><collection>Istex</collection><collection>Pascal-Francis</collection><collection>CrossRef</collection><jtitle>Journal of chemical and engineering data</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Comelli, Fabio</au><au>Francesconi, Romolo</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Isothermal Vapor−Liquid Equilibria Measurements, Excess Molar Enthalpies, and Excess Molar Volumes of Dimethyl Carbonate + Methanol, + Ethanol, and + Propan-1-ol at 313.15 K</atitle><jtitle>Journal of chemical and engineering data</jtitle><addtitle>J. Chem. Eng. Data</addtitle><date>1997-07-14</date><risdate>1997</risdate><volume>42</volume><issue>4</issue><spage>705</spage><epage>709</epage><pages>705-709</pages><issn>0021-9568</issn><eissn>1520-5134</eissn><coden>JCEAAX</coden><abstract>Isothermal vapor−liquid equilibria (VLE), excess molar enthalpies, , and excess molar volumes, , have been measured for the binary mixtures dimethyl carbonate + methanol, + ethanol, or + propan-1-ol at 313.15 K and at atmospheric pressure. The three mixtures exhibit large deviations from ideality, showing an azeotrope at 0.14, 0.42, and 0.78 mole fraction of dimethyl carbonate, respectively. The VLE data were correlated by the Wilson equation and the appropriate parameters are reported. and values have been correlated using the Redlich−Kister equation by the method of least-squares.</abstract><cop>Washington, DC</cop><pub>American Chemical Society</pub><doi>10.1021/je960321j</doi><tpages>5</tpages></addata></record>
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subjects	Chemistry Exact sciences and technology General and physical chemistry Liquid-vapor equilibria Phase equilibria
title	Isothermal Vapor−Liquid Equilibria Measurements, Excess Molar Enthalpies, and Excess Molar Volumes of Dimethyl Carbonate + Methanol, + Ethanol, and + Propan-1-ol at 313.15 K
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