Isothermal Vapor−Liquid Equilibria, Excess Molar Enthalpies, and Excess Molar Volumes of Trichloromethane + 1,2-Epoxybutane at (288.15, 298.15, and 313.15) K

Isothermal Vapor−Liquid Equilibria, Excess Molar Enthalpies, and Excess Molar Volumes of Trichloromethane + 1,2-Epoxybutane at (288.15, 298.15, and 313.15) K

Isothermal vapor−liquid equilibria, VLE, excess Gibbs energies, , excess molar enthalpies, , and excess molar volumes, , were determined for the binary mixture trichloromethane + 1,2-epoxybutane at (288.15, 298.15, and 313.15) K and at atmospheric pressure. All excess properties are negative. The va...

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Veröffentlicht in:Journal of chemical and engineering data 1996-03, Vol.41 (2), p.310-314
Hauptverfasser: Francesconi, R, Lunelli, B, Comelli, F
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Sprache:eng
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Chemistry
Exact sciences and technology
General and physical chemistry
Liquid-vapor equilibria
Phase equilibria
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container_title Journal of chemical and engineering data
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creator Francesconi, R
Lunelli, B
Comelli, F
description Isothermal vapor−liquid equilibria, VLE, excess Gibbs energies, , excess molar enthalpies, , and excess molar volumes, , were determined for the binary mixture trichloromethane + 1,2-epoxybutane at (288.15, 298.15, and 313.15) K and at atmospheric pressure. All excess properties are negative. The vapor−liquid equilibrium data are thermodynamically consistent and have been fitted to the Redlich−Kister equation. The influence of temperature has been discussed, and the relative magnitudes and signs of the excess properties have been outlined in terms of molecular interactions. Smooth representations of the results are presented.
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subjects Chemistry
Exact sciences and technology
General and physical chemistry
Liquid-vapor equilibria
Phase equilibria
title Isothermal Vapor−Liquid Equilibria, Excess Molar Enthalpies, and Excess Molar Volumes of Trichloromethane + 1,2-Epoxybutane at (288.15, 298.15, and 313.15) K
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