Reevaluation of Vapor−Liquid Equilibria for Butadiene + Styrene
In order to correct the system pressures predicted for butadiene + styrene by the model proposed by Wilhelm and Collier (1948), a different approach has been adopted to evaluate the liquid activity coefficients for butadiene and styrene using their reported pressure measurement for butadiene + styre...
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Veröffentlicht in: | Journal of chemical and engineering data 1996-03, Vol.41 (2), p.287-291 |
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container_title | Journal of chemical and engineering data |
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creator | Lu, Benjamin C.-Y Ni, Long-Wen Taylor, Mike |
description | In order to correct the system pressures predicted for butadiene + styrene by the model proposed by Wilhelm and Collier (1948), a different approach has been adopted to evaluate the liquid activity coefficients for butadiene and styrene using their reported pressure measurement for butadiene + styrene at 0 °C, and a simple temperature function has been used for extrapolating these liquid activity coefficients to higher temperatures. The validity of the proposed approach is verified by some of the hitherto proprietary experimental results. |
doi_str_mv | 10.1021/je9502197 |
format | Article |
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The validity of the proposed approach is verified by some of the hitherto proprietary experimental results.</description><identifier>ISSN: 0021-9568</identifier><identifier>EISSN: 1520-5134</identifier><identifier>DOI: 10.1021/je9502197</identifier><identifier>CODEN: JCEAAX</identifier><language>eng</language><publisher>Washington, DC: American Chemical Society</publisher><subject>Chemistry ; Exact sciences and technology ; General and physical chemistry ; Liquid-vapor equilibria ; Phase equilibria</subject><ispartof>Journal of chemical and engineering data, 1996-03, Vol.41 (2), p.287-291</ispartof><rights>Copyright © 1996 American Chemical Society</rights><rights>1996 INIST-CNRS</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-a239t-6099d7fde6db750882eb813ff9f6d5ad0bcd2701bec29c380e9d1478c44a69ae3</citedby><cites>FETCH-LOGICAL-a239t-6099d7fde6db750882eb813ff9f6d5ad0bcd2701bec29c380e9d1478c44a69ae3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://pubs.acs.org/doi/pdf/10.1021/je9502197$$EPDF$$P50$$Gacs$$H</linktopdf><linktohtml>$$Uhttps://pubs.acs.org/doi/10.1021/je9502197$$EHTML$$P50$$Gacs$$H</linktohtml><link.rule.ids>314,776,780,2752,27053,27901,27902,56713,56763</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=3026207$$DView record in Pascal Francis$$Hfree_for_read</backlink></links><search><creatorcontrib>Lu, Benjamin C.-Y</creatorcontrib><creatorcontrib>Ni, Long-Wen</creatorcontrib><creatorcontrib>Taylor, Mike</creatorcontrib><title>Reevaluation of Vapor−Liquid Equilibria for Butadiene + Styrene</title><title>Journal of chemical and engineering data</title><addtitle>J. Chem. Eng. Data</addtitle><description>In order to correct the system pressures predicted for butadiene + styrene by the model proposed by Wilhelm and Collier (1948), a different approach has been adopted to evaluate the liquid activity coefficients for butadiene and styrene using their reported pressure measurement for butadiene + styrene at 0 °C, and a simple temperature function has been used for extrapolating these liquid activity coefficients to higher temperatures. The validity of the proposed approach is verified by some of the hitherto proprietary experimental results.</description><subject>Chemistry</subject><subject>Exact sciences and technology</subject><subject>General and physical chemistry</subject><subject>Liquid-vapor equilibria</subject><subject>Phase equilibria</subject><issn>0021-9568</issn><issn>1520-5134</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>1996</creationdate><recordtype>article</recordtype><recordid>eNptj8tOwzAQRS0EEqWw4A-ygAVCAdtJ7HhZqvKQIoFoeYiNNfFDcilJsRNE_4A1n8iXkCqoKzZzRzNn7ugidEjwGcGUnM-NyDoVfAsNSEZxnJEk3UYD3A1jkbF8F-2FMMcYp5ySARrdG_MBixYaV1dRbaNHWNb-5-u7cO-t09GkqwtXegeRrX100TagnalMdBpNm5Xvun20Y2ERzMGfDtHD5WQ2vo6L26ub8aiIgSaiiRkWQnOrDdMlz3CeU1PmJLFWWKYz0LhUmnJMSqOoUEmOjdAk5blKU2ACTDJEJ72v8nUI3li59O4N_EoSLNfZ5SZ7xx717BKCgoX1UCkXNgcJpoziNRb3mAuN-dyswb9KxhOeydndVBbPhLOXp6kcd_xxz4MKcl63vuoC__P-F8ROdFg</recordid><startdate>19960312</startdate><enddate>19960312</enddate><creator>Lu, Benjamin C.-Y</creator><creator>Ni, Long-Wen</creator><creator>Taylor, Mike</creator><general>American Chemical Society</general><scope>BSCLL</scope><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>19960312</creationdate><title>Reevaluation of Vapor−Liquid Equilibria for Butadiene + Styrene</title><author>Lu, Benjamin C.-Y ; Ni, Long-Wen ; Taylor, Mike</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-a239t-6099d7fde6db750882eb813ff9f6d5ad0bcd2701bec29c380e9d1478c44a69ae3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>1996</creationdate><topic>Chemistry</topic><topic>Exact sciences and technology</topic><topic>General and physical chemistry</topic><topic>Liquid-vapor equilibria</topic><topic>Phase equilibria</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Lu, Benjamin C.-Y</creatorcontrib><creatorcontrib>Ni, Long-Wen</creatorcontrib><creatorcontrib>Taylor, Mike</creatorcontrib><collection>Istex</collection><collection>Pascal-Francis</collection><collection>CrossRef</collection><jtitle>Journal of chemical and engineering data</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Lu, Benjamin C.-Y</au><au>Ni, Long-Wen</au><au>Taylor, Mike</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Reevaluation of Vapor−Liquid Equilibria for Butadiene + Styrene</atitle><jtitle>Journal of chemical and engineering data</jtitle><addtitle>J. Chem. Eng. Data</addtitle><date>1996-03-12</date><risdate>1996</risdate><volume>41</volume><issue>2</issue><spage>287</spage><epage>291</epage><pages>287-291</pages><issn>0021-9568</issn><eissn>1520-5134</eissn><coden>JCEAAX</coden><abstract>In order to correct the system pressures predicted for butadiene + styrene by the model proposed by Wilhelm and Collier (1948), a different approach has been adopted to evaluate the liquid activity coefficients for butadiene and styrene using their reported pressure measurement for butadiene + styrene at 0 °C, and a simple temperature function has been used for extrapolating these liquid activity coefficients to higher temperatures. The validity of the proposed approach is verified by some of the hitherto proprietary experimental results.</abstract><cop>Washington, DC</cop><pub>American Chemical Society</pub><doi>10.1021/je9502197</doi><tpages>5</tpages></addata></record> |
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subjects | Chemistry Exact sciences and technology General and physical chemistry Liquid-vapor equilibria Phase equilibria |
title | Reevaluation of Vapor−Liquid Equilibria for Butadiene + Styrene |
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