Thermochemistry of Morpholine Adducts of Some Bivalent Transition Metal Bromides

Thermochemistry of Morpholine Adducts of Some Bivalent Transition Metal Bromides

The adducts [MBr2(morph) n ] (where M is Mn(II), Fe(II), Co(II), Ni(II), Cu(II), or Zn(II), morph is morpholine, and n = 1.5, 2, or 3) were synthesized and characterized by melting points, elemental analysis, thermal analysis, and electronic and IR spectroscopy. From calorimetric studies in solution...

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Veröffentlicht in:Journal of chemical and engineering data 2009-03, Vol.54 (3), p.842-846
1. Verfasser: Dunstan, P. Oliver
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Chemistry
Coordination compounds
Exact sciences and technology
Inorganic chemistry and origins of life
Preparations and properties
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description The adducts [MBr2(morph) n ] (where M is Mn(II), Fe(II), Co(II), Ni(II), Cu(II), or Zn(II), morph is morpholine, and n = 1.5, 2, or 3) were synthesized and characterized by melting points, elemental analysis, thermal analysis, and electronic and IR spectroscopy. From calorimetric studies in solution, the standard enthalpies of formation of the adducts and several thermochemical parameters were determined. The mean standard enthalpies of the metal−nitrogen bond were calculated.
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Oliver</creatorcontrib><title>Thermochemistry of Morpholine Adducts of Some Bivalent Transition Metal Bromides</title><title>Journal of chemical and engineering data</title><addtitle>J. Chem. Eng. Data</addtitle><description>The adducts [MBr2(morph) n ] (where M is Mn(II), Fe(II), Co(II), Ni(II), Cu(II), or Zn(II), morph is morpholine, and n = 1.5, 2, or 3) were synthesized and characterized by melting points, elemental analysis, thermal analysis, and electronic and IR spectroscopy. From calorimetric studies in solution, the standard enthalpies of formation of the adducts and several thermochemical parameters were determined. 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subjects Chemistry
Coordination compounds
Exact sciences and technology
Inorganic chemistry and origins of life
Preparations and properties
title Thermochemistry of Morpholine Adducts of Some Bivalent Transition Metal Bromides
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