Separation of a Phenol/o-Chlorophenol Mixture through Hydrotropy

A comprehensive study on the effect of hydrotropes such as urea, citric acid, sodium salicylate, and nicotinamide on the separation of phenol from phenol/o-chlorophenol mixtures under a wide range of hydrotrope concentrations, (0 to 3.0) mol·L−1, and different system temperatures, (303 to 333) K, ha...

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Veröffentlicht in:Journal of chemical and engineering data 2009-06, Vol.54 (6), p.1923-1926
Hauptverfasser: Jenamayjayan, D, Jayakumar, C, Gandhi, N. Nagendra
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container_end_page 1926
container_issue 6
container_start_page 1923
container_title Journal of chemical and engineering data
container_volume 54
creator Jenamayjayan, D
Jayakumar, C
Gandhi, N. Nagendra
description A comprehensive study on the effect of hydrotropes such as urea, citric acid, sodium salicylate, and nicotinamide on the separation of phenol from phenol/o-chlorophenol mixtures under a wide range of hydrotrope concentrations, (0 to 3.0) mol·L−1, and different system temperatures, (303 to 333) K, has been undertaken. The performance of hydrotropes toward separation of phenol was measured in terms of the Setschenow constant K S. A Minimum Hydrotrope Concentration (MHC) in the aqueous phase was found essential to initiate significant separation of phenol from the phenol/o-chlorophenol mixture. The maximum enhancement factor which is the ratio of the percentage extraction value in the presence and absence of a hydrotrope has been determined for each case.
doi_str_mv 10.1021/je800421y
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subjects Applied sciences
Chemical engineering
Exact sciences and technology
Liquid-liquid extraction
title Separation of a Phenol/o-Chlorophenol Mixture through Hydrotropy
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